Removal of antimonite and antimonate from water using Fe-based metal-organic frameworks: The relationship between framework structure and adsorption performance

被引:49
作者
Zhang, Wei [1 ,2 ,3 ]
Li, Na [1 ,2 ,3 ]
Xiao, Ting [1 ,2 ,3 ]
Tang, Wenting [1 ,2 ,3 ]
Xiu, Guangli [1 ,2 ,3 ]
机构
[1] East China Univ Sci & Technol, Sch Resources & Environm Engn, State Environm Protect Key Lab Environm Risk Asse, Shanghai 200237, Peoples R China
[2] Tongji Univ, Shanghai Inst Pollut Control & Ecol Secur, Shanghai 200092, Peoples R China
[3] East China Univ Sci & Technol, Shanghai Environm Protect Key Lab Environm Stand, Shanghai 200237, Peoples R China
来源
JOURNAL OF ENVIRONMENTAL SCIENCES | 2019年 / 86卷
基金
上海市自然科学基金; 中国国家自然科学基金;
关键词
Metal organic frameworks; MIL-101(Fe); Antimonite; Antimonate; Cage windows; Steric hindrance; AQUEOUS-SOLUTION; ZIRCONIUM-OXIDE; CU-BTC; SB(V); SB(III); IRON; MIL-100(FE); SURFACE; OXIDATION; ANTIMONY(III);
D O I
10.1016/j.jes.2019.06.001
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
We investigated the adsorption performance of five Fe-based MOFs (Fe-BTC, MIL-100(Fe), MIL-101(Fe), MIL-53(Fe) and MIL-88C(Fe)) for removal of antimonite (Sb(III)) and antimonate (Sb(V)) from water. Among these MOFs, MIL-101(Fe) exhibited the best adsorption capacities for both Sb(III) and Sb(V) (151.8 and 472.8 mg/g, respectively) which were higher than those of most adsorbents previously reported. The effect of steric hindrance was evident during Sb removal using the Fe-based MOFs, and the proper diameter of the smallest cage windows/channels should be considered an important parameter during the evaluation and selection of MOFs. Additionally, the adsorption capacities of MIL-101(Fe) for Sb(V) decreased with increasing initial pH values (from 3.0 to 8.0), while the opposite trend was observed for Sb(III). Chloride, nitrate and sulfate ions had a negligible influence on Sb(V) adsorption, while NO3- and SO42- improved Sb(III) adsorption. This result implies that inner sphere complexes might form during both Sb(III) and Sb(V) adsorption. (c) 2019 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V.
引用
收藏
页码:213 / 224
页数:12
相关论文
共 64 条
  • [1] Iron terephthalate metal-organic framework: Revealing the effective activation of hydrogen peroxide for the degradation of organic dye under visible light irradiation
    Ai, Lunhong
    Zhang, Caihong
    Li, Lili
    Jiang, Jing
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2014, 148 : 191 - 200
  • [2] An Y.L., 2011, J MATER RES, V9, P2745
  • [3] Cu-BTC and Fe-BTC metal-organic frameworks: Role of the materials structural features on their performance for volatile hydrocarbons separation
    Autie-Castro, G.
    Autie, M. A.
    Rodriguez-Castellon, E.
    Aguirre, C.
    Reguera, E.
    [J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2015, 481 : 351 - 357
  • [4] Understanding the Colloidal Stability of the Mesoporous MIL-100(Fe) Nanoparticles in Physiological Media
    Bellido, Elena
    Guillevic, Mazheva
    Hidalgo, Tania
    Santander-Ortega, Manuel J.
    Serre, Christian
    Horcajada, Patricia
    [J]. LANGMUIR, 2014, 30 (20) : 5911 - 5920
  • [5] Selective adsorption of arsenate and the reversible structure transformation of the mesoporous metal-organic framework MIL-100(Fe)
    Cai, Jianhua
    Wang, Xueyun
    Zhou, Yue
    Jiang, Li
    Wang, Chunru
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2016, 18 (16) : 10864 - 10867
  • [6] Rationale of Drug Encapsulation and Release from Biocompatible Porous Metal-Organic Frameworks
    Cunha, Denise
    Ben Yahia, Mouna
    Hall, Shaun
    Miller, Stuart R.
    Chevreau, Hubert
    Elkaim, Erik
    Maurin, Guillaume
    Horcajada, Patricia
    Serre, Christian
    [J]. CHEMISTRY OF MATERIALS, 2013, 25 (14) : 2767 - 2776
  • [7] Antimonate removal from water using hierarchical macro-/mesoporous amorphous alumina
    Dou, Xiaomin
    Mohan, Dinesh
    Zhao, Xueqin
    Pittman, Charles U., Jr.
    [J]. CHEMICAL ENGINEERING JOURNAL, 2015, 264 : 617 - 624
  • [8] Removal of antimony (III) from polluted surface water using a hybrid coagulation-flocculation-ultrafiltration (CF-UF) process
    Du, Xing
    Qu, Fangshu
    Liang, Heng
    Li, Kai
    Yu, Huarong
    Bai, Langming
    Li, Guibai
    [J]. CHEMICAL ENGINEERING JOURNAL, 2014, 254 : 293 - 301
  • [9] Antimony in the environment: A review focused on natural waters. III. Microbiota relevant interactions
    Filella, Montserrat
    Belzile, Nelson
    Lett, Marie-Claire
    [J]. EARTH-SCIENCE REVIEWS, 2007, 80 (3-4) : 195 - 217
  • [10] Hydrogen-bonding-induced efficient dispersive solid phase extraction of bisphenols and their derivatives in environmental waters using surface amino-functionalized MIL-101(Fe)
    Gao, Man
    Liu, Wei
    Wang, Xuran
    Li, Yanyan
    Zhou, Peipei
    Shi, Liwan
    Ye, Buxing
    Dahlgren, Randy A.
    Wang, Xuedong
    [J]. MICROCHEMICAL JOURNAL, 2019, 145 : 1151 - 1161