Organic-inorganic hybrids constructed of anderson-type polyoxoanions and oxalato-bridged dinuclear copper complexes

被引：106

作者：

Cao, Ruige ^{[1
]}

Liu, Shuxia ^{[1
]}

Xie, Linhua ^{[1
]}

Pan, Yibing ^{[1
]}

Cao, Jianfang ^{[1
]}

Ren, Yuanhang ^{[1
]}

Xu, Lin ^{[1
]}

机构：

[1] NE Normal Univ, Coll Chem, Key Lab Polyoxometalates Sci, Minist Educ, Changchun 130024, Jilin, Peoples R China

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 09期

关键词：

D O I：

10.1021/ic062208c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel organic-inorganic hybrid compounds based on Anderson-type polyoxoanions, [Cu-2(bpy)(2)(mu-ox)][Al(OH)(7)Mo6O17] (1) and [Cu-2(bpy)(2)(mu-ox)][Cr(OH)(7)Mo6O17] (2), have been synthesized and characterized by elemental analyses, IR, and X-ray powder diffraction. The crystal structures of 1 and 2 have been established by single-crystal X-ray diffraction, which reveals the presence of 1D chains constructed of alternating Anderson-type polyoxoanions and oxalato-bridged dinuclear copper complexes for both compounds and extensive hydrogen bonding that plays an important role in the formation of the 3D supramolecular network structures of 1 and 2. To elucidate the electronic properties and magnetic properties of the metal ions (Cu2+ or Cu2+ and Cr3+), EPR studies and magnetic susceptibility studies have been performed, respectively. The results are consistent with the structural feature of these compounds.

引用

页码：3541 / 3547

页数：7

共 57 条

[1] OXALATO-BRIDGED AND RELATED DINUCLEAR COPPER(II) COMPLEXES - THEORETICAL-ANALYSIS OF THEIR STRUCTURES AND MAGNETIC COUPLING [J].