Synthesis and characterization of novel magnetic Fe3O4/polyphosphazene nanofibers

被引：18

作者：

Zhang, Xiaoyan ^{[1
]}

Dai, Qiaoyu ^{[1
]}

Huang, Xiaobin ^{[1
]}

Tang, Xiaozhen ^{[1
,2
]}

机构：

[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China

[2] Shanghai Jiao Tong Univ, Natl Key Lab Met Matrix Composite Mat, Shanghai 200240, Peoples R China

来源：

SOLID STATE SCIENCES | 2009年 / 11卷 / 11期

关键词：

Magnetic particles; Polymer nanofibers; Superparamagnetic; Ultrasonic irradiation; Polyphosphazene; POLYMER NANOFIBERS; CYCLOTRIPHOSPHAZENE PLATFORM; COMPLEXES; ORIENTATION; FABRICATION; NANOWIRES; FIBERS; NICKEL; CHARGE;

D O I：

10.1016/j.solidstatesciences.2009.08.003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel magnetic Fe3O4/polyphosphazene nanofibers were successfully prepared via a facile approach by ultrasonic irradiation. The structure and morphology were characterized by SEM, TEM, EDX, IR and XRD. The characterization results show that the magnetic Fe3O4/polyphosphazene nanofibers are several microns in length and 50-100 nm in diameter with Fe3O4 nanoparticles of 5-10 nm attached on the surface. The interaction between Fe3O4 nanoparticles and polyphosphazene nanofibers was thought as coordination behavior. TG curves show that the magnetic Fe3O4/polyphosphazene nanofibers have good thermostability and high magnetism content of about 44%. Magnetic studies show that the magnetic nanofibers exhibit good superparamagnetic properties with high magnetization saturation value of about 36 emu/g. (C) 2009 Elsevier Masson SAS. All rights reserved.

引用

页码：1861 / 1865

页数：5

共 28 条

[1] Copper complexes with 1,10-phenanthrolines tethered to a cyclotriphosphazene platform [J].

Ainscough, Eric W. ;

Brodie, Andrew M. ;

Jameson, Geoffrey B. ;

Otter, Carl A. .

POLYHEDRON, 2007, 26 (02) :460-471

[2] Divalent cobalt, nickel and zinc halide complexes with multimodal ligands based on the cyclotriphosphazene platform: A structural study [J].

Ainscough, Eric W. ;

Brodie, Andrew M. ;

Depree, Craig V. ;

Otter, Carl A. .

POLYHEDRON, 2006, 25 (11) :2341-2352

[3] Polymer building blocks: Self-assembly of silver(I) cyclotriphosphazene cationic columns [J].

Ainscough, EW ;

Brodie, AM ;

Depree, CV ;

Jameson, GB ;

Otter, CA .

INORGANIC CHEMISTRY, 2005, 44 (21) :7325-7327

[4] Polymer nanofibers and nanotubes: Charge transport and device applications [J].

Aleshin, AN .

ADVANCED MATERIALS, 2006, 18 (01) :17-27

[5] Electrospun nanofibers of blends of conjugated polymers: Morphology, optical properties, and field-effect transistors [J].

Babel, A ;

Li, D ;

Xia, YN ;

Jenekhe, SA .

MACROMOLECULES, 2005, 38 (11) :4705-4711

[6] Evidence for molecular orientation and residual charge in the electrospinning of poly(butylene terephthalate) nanofibers [J].

Catalani, Luiz H. ;

Collins, George ;

Jaffe, Michael .

MACROMOLECULES, 2007, 40 (05) :1693-1697

[7] Polymeric nanofibers prepared from self-organized supramolecules [J].

de Moel, K ;

van Ekenstein, GORA ;

Nijland, H ;

Polushkin, E ;

ten Brinke, G ;

Mäki-Ontto, R ;

Ikkala, O .

CHEMISTRY OF MATERIALS, 2001, 13 (12) :4580-4583

[8] Rapid fabrication and formation mechanism of cyclotriphosphazene-containing polymer nanofibers [J].

Fu, Jianwei ;

Huang, Xiaobin ;

Zhu, Yan ;

Huang, Yawen ;

Zhu, Lu ;

Tang, Xiaozhen .

EUROPEAN POLYMER JOURNAL, 2008, 44 (11) :3466-3472

[9] Control of thickness and orientation of solution-grown silicon nanowires [J].

Holmes, JD ;

Johnston, KP ;

Doty, RC ;

Korgel, BA .

SCIENCE, 2000, 287 (5457) :1471-1473

[10] A review on polymer nanofibers by electrospinning and their applications in nanocomposites [J].

Huang, ZM ;

Zhang, YZ ;

Kotaki, M ;

Ramakrishna, S .

COMPOSITES SCIENCE AND TECHNOLOGY, 2003, 63 (15) :2223-2253

← 1 2 3 →