Influence of Magnesium Hydroxide and Huntite Hydromagnesite on Mechanical Properties of Ethylene Vinyl Acetate Compounds Cross-linked by DiCumyl Peroxide and Ionizing Radiation

被引:30
作者
Basfar, A. A. [1 ]
Bae, H. J. [1 ]
机构
[1] King Abdulaziz City Sci & Technol, Atom Energy Res Inst, Radiat Technol Ctr, Riyadh 11442, Saudi Arabia
关键词
magnesium hydroxide; huntite hydromagnesite; halogen free; wire and cable; EVA; flame retardancy; MICROENCAPSULATED RED PHOSPHORUS; FLAME; MONTMORILLONITE;
D O I
10.1177/0734904109340765
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Flame retardants including magnesium hydroxide (MH) and huntite hydromagnesite (HH) were used to develop halogen free flame retardant (HFFR) compounds based on ethylene vinyl acetate (EVA) for wire and cable applications. Cone calorimeter and limiting oxygen index (LOI) results show that cross-linking affects not only mechanical properties, but also flame retardancy. Consequently, flame retardancy is mainly influenced by type of flame retardants and mixing ratio of base polymers and to a lesser extent by cross-linking. Tensile strength increased with increase of MH, while elongation at break decreased with increase of MH in cross-linked formulations. On the other hand, elongation at break increased with increase of HH while tensile strength decreased with increase of HH in cross-linked formulations. HFFR compounds with tensile strength of 12 MPa, elongation at break of 200%, LOI of 40% was developed to meet the stringent specifications of wire and cable industry.
引用
收藏
页码:161 / 180
页数:20
相关论文
共 15 条
[1]  
[Anonymous], 2004, 605021 IEC
[2]  
*BRIT STAND, 1998, 6724 BS
[3]   Effects of polystyrene-encapsulated magnesium hydroxide on rheological and flame-retarding properties of HIPS composites [J].
Chang, Suqin ;
Xie, Tingxiu ;
Yang, Guisheng .
POLYMER DEGRADATION AND STABILITY, 2006, 91 (12) :3266-3273
[4]  
COGEN JM, 2006, Patent No. 2006026256
[5]   Flammability characteristics and synergistic effect of hydrotalcite with microencapsulated red phosphorus in halogen-free flame retardant EVA composite [J].
Du, LC ;
Qu, BJ ;
Xu, ZJ .
POLYMER DEGRADATION AND STABILITY, 2006, 91 (05) :995-1001
[6]   Study of hydromagnesite and magnesium hydroxide based fire retardant systems for ethylene-vinyl acetate containing organo-modified montmorillonite [J].
Laoutid, F. ;
Gaudon, P. ;
Taulemesse, J-M. ;
Cuesta, J. M. Lopez ;
Velasco, J. I. ;
Piechaczyk, A. .
POLYMER DEGRADATION AND STABILITY, 2006, 91 (12) :3074-3082
[7]   Melamine cyanurate-microencapsulated red phosphorus flame retardant unreinforced and glass fiber reinforced polyamide 66 [J].
Liu, Yuan ;
Wang, Qi .
POLYMER DEGRADATION AND STABILITY, 2006, 91 (12) :3103-3109
[8]  
LOMAKIN SM, 2003, MODERN POLYM FLAME R, P159
[9]  
LUCIANA R, 2005, POLYM DEGRADATION ST, V88, P444
[10]   Studies of ABS-graft-maleic anhydride/clay nanocomposites: Morphologies, thermal stability and flammability properties [J].
Ma, Haiyun ;
Xu, Zhongbin ;
Tong, Lifang ;
gu, Aian Gu ;
Fang, Zhengping .
POLYMER DEGRADATION AND STABILITY, 2006, 91 (12) :2951-2959