Synthesis and Crystal Structure of Trans-bis(acesulfamato-O)tetraaquazinc(II)

被引：0
作者：
Sahin, Onur [1 ]
Icbudak, Hasan [2 ]
Buyukgungor, Orhan [1 ]
机构：
[1] Ondokuz Mayis Univ, Fac Arts & Sci, Dept Phys, Samsun, Turkey
[2] Ondokuz Mayis Univ, Fac Arts & Sci, Dept Chem, Samsun, Turkey
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2010年 / 29卷 / 07期
关键词：
crystal structure; zinc(II); octahedral; complex; hydrogen bonds; ACESULFAMATE;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The title compound, trans-bis(acesulfamato-O)tetraaquazinc(II) (I, C8H16N2O12S2Zn), crystallizes in the triclinic system, space group P (1) over bar with a = 5.1638(5), b = 8.5338(9), c = 9.9583(9) angstrom, alpha = 74.325(8), beta = 81.112(7), gamma = 75.800(8)degrees, V = 407.77(7) angstrom(3), Z = 1, F(000) = 236, R-int = 0.085, T = 296 K, the final R = 0.029 and wR = 0.078 for 1832 observed reflections with I > 2 sigma(I). The Zn-II centre resides on a centre of symmetry and has a distorted octahedral geometry. The basal plane is defined by two carbonyl 0 atoms of two monodentate trans-oriented acesulfamato ligands and two trans-aqua ligands. The axial positions in the octahedron are occupied by two trans-aqua ligands. Intermolecular O-H center dot center dot center dot O hydrogen bonds produce R-2(2)(8) and R-2(2)(16) rings, which lead to two-dimensional polymeric chains.
引用
收藏
页码：1047 / 1050
页数：4
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