1-[1-(4-Bromophenyl)ethylidene]-4-(2,4-dimethoxyphenyl)thiosemicarbazide

被引:1
作者
Yaqub, Muhammad [2 ]
Pervez, Humayun [2 ]
Arif, Nadia [2 ]
Tahir, M. Nawaz [1 ]
Hussain, Mazhar [2 ]
机构
[1] Univ Sargodha, Dept Phys, Sargodha, Pakistan
[2] Bahauddin Zakariya Univ, Dept Chem, Multan 60800, Pakistan
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词
D O I
10.1107/S1600536810022622
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C17H18BrN3O2S, the dihedral angle between the aromatic rings is 9.15 (17)degrees. A bifurcated intramolecular N-H center dot center dot center dot(N,O) hydrogen bond generates two S(5) rings and a weak intramolecular C-H center dot center dot center dot S interaction completes an S(6) ring motif. In the crystal, inversion dimers linked by pairs of N-H center dot center dot center dot S hydrogen bonds generate R-2(2)(8) loops and weak C-H center dot center dot center dot S and C-H center dot center dot center dot pi interactions are also present.
引用
收藏
页码:O1696 / U510
页数:10
相关论文
共 13 条
[1]  
[Anonymous], 2005, SADABS
[2]   The wide pharmacological versatility of semicarbazones, thiosemicarbazones and their metal complexes [J].
Beraldo, H ;
Gambino, D .
MINI-REVIEWS IN MEDICINAL CHEMISTRY, 2004, 4 (01) :31-39
[3]   PATTERNS IN HYDROGEN BONDING - FUNCTIONALITY AND GRAPH SET ANALYSIS IN CRYSTALS [J].
BERNSTEIN, J ;
DAVIS, RE ;
SHIMONI, L ;
CHANG, NL .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (15) :1555-1573
[4]  
Bruker, 2007, APEX2 SAINT
[5]  
Farrugia L.J., 1997, J. Appl. Crystallogr., V30, P565, DOI [10.1107/S0021889897003117, DOI 10.1107/S0021889897003117]
[6]  
Farrugia L. J., 1999, Journal of Applied Crystallography, V32, P837, DOI [DOI 10.1107/S0021889812029111, 10.1107/S0021889899006020, DOI 10.1107/S0021889899006020]
[7]   4-Phenyl-1-(1-phenylethylidene)thiosemicarbazide [J].
Jian, FF ;
Li, Y ;
Xiao, HL .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2005, 61 :O2219-O2220
[8]   Synthesis, characterization and solid state structures of thiosemicarbazone palladacycles:: Influence of hydrogen bonding in the molecular arrangement [J].
Martinez, Javier ;
Adrio, Luis A. ;
Antelo, Jose M. ;
Ortigueira, Juan M. ;
Pereira, Teresa ;
Lopez-Torres, Margarita ;
Vila, Jose M. .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2006, 691 (13) :2891-2901
[9]   4-(5-Chloro-2-methylphenyl)-1-[2-oxo-5-(trifluoromethoxy)indolin-3-ylidene]thiosemicarbazide [J].
Pervez, Humayun ;
Iqbal, Mohammad S. ;
Saira, Naveeda ;
Yaqub, Muhammad ;
Tahir, M. Nawaz .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 :O1169-U907
[10]   Synthesis and Urease Inhibitory Properties of Some New N4-Substituted 5-Nitroisatin-3-thiosemicarbazones [J].
Pervez, Humayun ;
Manzoor, Nazia ;
Yaqub, Muhammad ;
Khan, Ajmal ;
Khan, Khalid Mohammed ;
Nasim, Faiz-ul-Hassan ;
Choudhary, M. Iqbal .
LETTERS IN DRUG DESIGN & DISCOVERY, 2010, 7 (02) :102-108