Di-μ1,1-azido-bis[(2-{1-[2-(isopropylamino)ethylimino]ethyl}phenolato)copper(II)]

被引：3

作者：

Li, He-Bing ^{[1
]}

机构：

[1] Xiangnan Univ, Dept Chem & Life Sci, Chenzhou 423000, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

MAGNETIC-PROPERTIES; STRUCTURAL-CHARACTERIZATION; AZIDO; COMPLEXES; BRIDGES;

D O I：

10.1107/S1600536810017174

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the centrosymmetric binuclear title complex, [Cu-2(C13H19N2O)(2)(N-3)(2)], the Cu-II atom adopts an elongated CuON4 square-based pyramidal coordination geometry, arising from the N,N',O-tridentate ligand and two bridging end-on azide anions. The O atom is in the basal plane, one of the azide N atoms is in the apical site and the Cu center dot center dot center dot Cu separation is 3.2365 (3) angstrom. A pair of intramolecular N-H center dot center dot center dot O hydrogen bonds helps to establish the molecular conformation.

引用

页码：M651 / U529

页数：11

共 17 条

[1]

Bruker, 1998, SMART SAINT SADABS

[2] Synthesis, characterization, and cytotoxic properties of platinum(II)-amine complexes.: X-ray crystal structure determination of [Pt(C6H12N4) Cl2] • 3H2O [J].

Cheng, Kui ;

Zhu, Hai-Liang ;

Li, Zhi-Bin .

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2006, 36 (10) :719-722

[3] Rational design of azide-bridged bimetallic complexes.: Crystal structure and magnetic properties of FeIIIMFeIII (M = NiII and CuII) trinuclear species [J].

Colacio, E ;

Costes, JP ;

Domínguez-Vera, JM ;

Ben Maimoun, I ;

Suárez-Varela, J .

CHEMICAL COMMUNICATIONS, 2005, (04) :534-536

[4] Antiferromagnetic alternating and homogeneous manganese-azido chains:: Structural characterization and magnetic behavior of two new one-dimensional [Mn(L)2(μ1,3-N3)2]n compounds (L = 3-ethylpyridine and 2-hydroxypyridine) [J].

Escuer, A ;

Vicente, R ;

Goher, MAS ;

Mautner, FA .

INORGANIC CHEMISTRY, 1998, 37 (04) :782-787

[5] Azide as a bridging ligand and magnetic coupler in transition metal clusters [J].

Escuer, Albert ;

Aromi, Guillem .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (23) :4721-4736

[6] One-dimensional copper(II) complexes containing only single end-on azido bridges: Crystal structures and magnetic properties [J].

Gao, EQ ;

Yue, YF ;

Bai, SQ ;

He, Z ;

Yan, CH .

CRYSTAL GROWTH & DESIGN, 2005, 5 (03) :1119-1124

[7] Synthesis, spectral, magnetic and crystal structural characterization of two new copper(II) azido complexes:: catena-[μ(N3)Cu(pyridine)3]n(PF6)n and dimeric [Cu(4-ethylpyridine)(N3)2]2 [J].

Goher, MAS ;

Escuer, A ;

Mautner, FA ;

Al-Salem, NA .

POLYHEDRON, 2001, 20 (24-25) :2971-2977

[8] Coexistence of spin canting and metamagnetism in a one-dimensional Mn(III) complex bridged by a single end-to-end azide [J].

Ko, Hyun Hee ;

Lim, Jeong Hak ;

Kim, Hyoung Chan ;

Hong, Chang Seop .

INORGANIC CHEMISTRY, 2006, 45 (22) :8847-8849

[9] Effect of cyanato, azido, carboxylato, and carbonato ligands on the formation of cobalt(II) polyoxometalates:: Characterization, magnetic, and electrochemical studies of multinuclear cobalt clusters [J].

Lisnard, Laurent ;

Mialane, Pierre ;

Dolbecq, Anne ;

Marrot, Jerome ;

Clemente-Juan, Juan Modesto ;

Coronado, Eugenio ;

Keita, Bineta ;

de Oliveira, Pedro ;

Nadjo, Louis ;

Secheresse, Francis .

CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (12) :3525-3536

[10] Dinuclear and polynuclear bridged azido-nickel(II) complexes: Synthesis, structure determination, and magnetic properties [J].

Massoud, Salah S. ;

Mautner, Franz A. ;

Vicente, Ramon ;

Gallo, August A. ;

Ducasse, Elodie .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2007, (08) :1091-1102

← 1 2 →