Preparation of diazoalkane complexes of osmium(II)

被引：28
作者：
Albertin, G [1 ]
Antoniutti, S [1 ]
Bordignon, E [1 ]
Carrera, B [1 ]
机构：
[1] Univ Venice, Dipartimento Chim, I-30123 Venice, Italy
来源：
INORGANIC CHEMISTRY | 2000年 / 39卷 / 20期
关键词：
D O I：
10.1021/ic991335o
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis of a series of diazoalkane complexes [OsH(N2CRR')P4]CF3SO3(P = phosphite) is reported. Spectroscopic characterization and substitution reaction affording new osmium [OsHLP4]+ derivatives are also dicussed.
引用
收藏
页码：4646 / 4650
页数：5
相关论文
共 59 条
[1]  
ALBERTIN G, 1994, GAZZ CHIM ITAL, V124, P355
[2]   PREPARATION AND PROPERTIES OF NEW DINITROGEN OSMIUM(II) COMPLEXES [J].
ALBERTIN, G ;
ANTONIUTTI, S ;
BALDAN, D ;
BORDIGNON, E .
INORGANIC CHEMISTRY, 1995, 34 (24) :6205-&
[3]   Synthesis, characterisation and reactivity of hydrazine complexes of iron(II) [J].
Albertin, G ;
Antoniutti, S ;
Bordignon, E ;
Pattaro, S .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (22) :4445-4453
[4]   Mono- and bis(hydrazine) complexes of osmium(II):: Synthesis, reactions, and X-ray crystal structure of the [Os(NH2NH2)2{P(OEt)3}4](BPh4)2 derivative [J].
Albertin, G ;
Antoniutti, S ;
Bacchi, A ;
Bergano, M ;
Bordignon, E ;
Pelizzi, G .
INORGANIC CHEMISTRY, 1998, 37 (03) :479-489
[5]   REACTIVITY OF NEW OSMIUM DIHYDRIDES WITH ARENEDIAZONIUM CATIONS - PREPARATION AND PROPERTIES OF BIS(ARYLDIAZENE) AND MONO(ARYLDIAZENIDO) COMPLEXES - A COMPARISON WITH ANALOGOUS IRON AND RUTHENIUM DERIVATIVES [J].
ALBERTIN, G ;
ANTONIUTTI, S ;
BORDIGNON, E .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (12) :2353-2358
[6]   Reactivity of hydrides FeH2(CO)2P2 (P = phosphites) with aryldiazonium cations:: Preparation, characterization, X-ray crystal structure, and electrochemical studies of mono- and binuclear aryldiazenido complexes [J].
Albertin, G ;
Antoniutti, S ;
Bacchi, A ;
Barbera, D ;
Bordignon, E ;
Pelizzi, G ;
Ugo, P .
INORGANIC CHEMISTRY, 1998, 37 (21) :5602-5610
[7]   Binuclear iron and ruthenium complexes with bis(diazene) or bis(diazenido) bridging ligands: Synthesis, characterization, X-ray crystal structure, and electrochemical studies [J].
Albertin, G ;
Antoniutti, S ;
Bacchi, A ;
Bordignon, E ;
Pelizzi, G ;
Ugo, P .
INORGANIC CHEMISTRY, 1996, 35 (21) :6245-6253
[8]   BIS(ARYLDIAZENE)RUTHENIUM AND RELATED MONO(ARYLDIAZENIDO)RUTHENIUM COMPLEXES - PREPARATION, CHARACTERIZATION, AND REACTIVITY - CRYSTAL-STRUCTURE OF [RU(4-CH3C6H4N=NH)2(P(OET)3)4](PF6)2 [J].
ALBERTIN, G ;
ANTONIUTTI, S ;
PELIZZI, G ;
VITALI, F ;
BORDIGNON, E .
INORGANIC CHEMISTRY, 1988, 27 (05) :829-835
[9]   SYNTHESIS AND CHARACTERIZATION OF ENYNYL, VINYL AND ACETYLIDE COMPLEXES OF OSMIUM(II) [J].
ALBERTIN, G ;
ANTONIUTTI, S ;
BORDIGNON, E .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (05) :719-725
[10]   MOLECULAR-HYDROGEN COMPLEXES - PREPARATION AND REACTIVITY OF NEW RUTHENIUM(II) AND OSMIUM(II) DERIVATIVES AND A COMPARISON ALONG THE IRON TRIAD [J].
AMENDOLA, P ;
ANTONIUTTI, S ;
ALBERTIN, G ;
BORDIGNON, E .
INORGANIC CHEMISTRY, 1990, 29 (02) :318-324
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