Synthesis of Nano-Hierarchical Ferrierite with Sole Template and Its Catalytic Application in n-Butene Skeletal Isomerization

被引：4

作者：

Liu, Wen ^{[1
]}

Hu, Haiqiang ^{[1
]}

Ke, Ming ^{[1
]}

Liu, Yang ^{[1
]}

Zhang, Lei ^{[1
]}

Xia, Chengjie ^{[1
]}

Wang, Qi ^{[1
]}

机构：

[1] China Univ Petr, State Key Lab Heavy Oil Proc, 18 Fuxue Rd, Beijing 102249, Peoples R China

来源：

CHEMISTRYSELECT | 2019年 / 4卷 / 34期

基金：

中国国家自然科学基金;

关键词：

FER; Hierarchical; Static; Sole OSDA; isomerization; ZEOLITE CATALYSTS; 1-BUTENE;

D O I：

10.1002/slct.201902455

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nano-hierarchical ferrierite(FER) was successfully synthesized by using pyrrolidine as sole organic structure directing(OSDA) agent under static hydrothermal conditions.SEM images showed that the morphology of the product was a loose three-stage accumulation structure by nano-rod crystal grains .The influence of crystallization temperature, gel alkalinity, crystallization time and the amount of OSDA on synthesis of FER was investigated in detail.Moreover,FER catalytic performance in n-butene skeletal isomerizatio was investigated.The results showed that, compared with the commercial FER, the nano-hierarchical FER showed better catalytic activity.

引用

页码：9972 / 9977

页数：6

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