Electron transfer behavior of calcined material obtained from a samarium-O-phenylene-S-nickel-S-phenylene-O hybrid copolymer

被引：35

作者：

Matsui, H.

Yamamoto, S.

Izawa, Y.

Karuppuchamy, S.

Yoshihara, M.

机构：

[1] Kinki Univ, Mol Engn Inst, Iizuka, Fukuoka 8208555, Japan

[2] Taki Chem Co Ltd, Kakogawa, Hyogo 6750125, Japan

[3] Kinki Univ, Dept Appl Chem, Fac Sci & Engn, Higashiosaka, Osaka 5778502, Japan

来源：

MATERIALS CHEMISTRY AND PHYSICS | 2007年 / 103卷 / 01期

关键词：

composite materials; semiconductors; nanostructures; polymers;

D O I：

10.1016/j.matchemphys.2007.01.022

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Calcination of a samarium-O-phenylene-S-nickel-S-phenylene-O hybrid copolymer under an argon atmosphere gave Sm2O3-carbon cluster-Ni3S4 composite material. ESR spectral examinations of the calcined materials revealed the possibility of a two-step electron transfer in the process Of Sm2O3 -> carbon cluster -> Ni3S4 with an oxidation site at Sm2O3 particles and a reduction site at Ni3S4 particles. The calcined material was found to reduce methylene blue under visible light irradiation. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：127 / 131

页数：5

共 22 条

[1] SUSTAINED WATER CLEAVAGE BY VISIBLE-LIGHT [J].