Studying and Evaluating Catalytic Pyrolysis of Polypropylene

被引:1
作者
Abdelrahman, Ameen [1 ]
Hamouda, Asmaa S. [2 ]
Mohamed, H. F. M. [3 ]
Zaki, A. H. [4 ]
机构
[1] Beni Suef Univ, Fac Postgrad Studies Adv Sci, Renewable Energy Sci & Engn Dept, POB 62511, Bani Suwayf, Egypt
[2] Beni Suef Univ, Fac Postgrad Studies Adv Sci, Dept Environm Sci & Ind Dev, POB 62511, Bani Suwayf, Egypt
[3] Minia Univ, Fac Sci, Phys Dept, POB 61519, Al Minya, Egypt
[4] Beni Suef Univ, Fac Postgrad Studies Adv Sci, Dept Mat Sci & Nanotechnol, POB 62511, Bani Suwayf, Egypt
来源
EGYPTIAN JOURNAL OF CHEMISTRY | 2021年 / 64卷 / 05期
关键词
Clay metal oxides; Nanocomposites; Catalytic thermochemical cracking; Plastic waste; Polypropylene; HIGH-DENSITY POLYETHYLENE; METHANOL ELECTROOXIDATION; PLASTIC WASTE; DEGRADATION; FUEL; RECOVERY; OIL; GASIFICATION; HYDROCARBONS; PERFORMANCE;
D O I
10.21608/EJCHEM.2021.48239.2988
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Renewable energy and alternative fuel from different conventional resources such as biomass, plastic waste, and recyclable polymers are impertinent environmental issues worldwide. Furthermore, to replace fossil fuel and reduce greenhouse gas emissions that have a negative impact on climate change. This article exhibits the effect of metal oxide composite/clay in the thermal decomposition of Polypropylene. That hetrocatalyst composed nano-clay thin layer loaded with MnO2-NPs works on cracking of polypropylene under different reaction conditions like heating temperature, rate of reaction, reaction time, and composite loading ratio. Various techniques such as GC and TEM were used to characterize pyrolysis gases and char, in addition to scanning electron microscopy (SEM), Fourier transform infrared (FTIR), Thermo-gravimetric analyzer (TGA), and X-ray diffraction (XRD) were used for composite characterize. High gas yield and char rate conversion were obtained using synthesize composite.
引用
收藏
页码:2593 / 2606
页数:14
相关论文
共 62 条
[1]   Fuels from Waste Plastics by Thermal and Catalytic Processes: A Review [J].
Aguado, J. ;
Serrano, D. P. ;
Escola, J. M. .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2008, 47 (21) :7982-7992
[2]   Catalytic cracking of polyethylene over zeolite mordenite with enhanced textural properties [J].
Aguado, J. ;
Serrano, D. P. ;
Escola, J. M. ;
Peral, A. .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2009, 85 (1-2) :352-358
[3]   Wax formation in the pyrolysis of polyolefins in a conical spouted bed reactor [J].
Aguado, R ;
Olazar, M ;
San José, MJ ;
Gaisán, B ;
Bilbao, J .
ENERGY & FUELS, 2002, 16 (06) :1429-1437
[4]   Pyrolysis Study of Polypropylene and Polyethylene Into Premium Oil Products [J].
Ahmad, Imtiaz ;
Khan, M. Ismail ;
Khan, Hizbullah ;
Ishaq, M. ;
Tariq, Razia ;
Gul, Kashif ;
Ahmad, Waqas .
INTERNATIONAL JOURNAL OF GREEN ENERGY, 2015, 12 (07) :663-671
[5]   A review on thermal and catalytic pyrolysis of plastic solid waste (PSW) [J].
Al-Salem, S. M. ;
Antelava, A. ;
Constantinou, A. ;
Manos, G. ;
Dutta, A. .
JOURNAL OF ENVIRONMENTAL MANAGEMENT, 2017, 197 :177-198
[6]  
[Anonymous], 2003, J. Mater. Cycles Waste Manage
[7]   Characterization of the waxes obtained by the pyrolysis of polyolefin plastics in a conical spouted bed reactor [J].
Arabiourrutia, M. ;
Elordi, G. ;
Lopez, G. ;
Borsella, E. ;
Bilbao, J. ;
Olazar, M. .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2012, 94 :230-237
[8]   Operating Conditions for the Pyrolysis of Poly-(ethylene terephthalate) in a Conical Spouted-Bed Reactor [J].
Artetxe, Maite ;
Lopez, Gartzen ;
Amutio, Maider ;
Elordi, Gorka ;
Olazar, Martin ;
Bilbao, Javier .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2010, 49 (05) :2064-2069
[9]   Steam and KOH activation of biochar: Experimental and modeling studies [J].
Azargohar, R. ;
Dalai, A. K. .
MICROPOROUS AND MESOPOROUS MATERIALS, 2008, 110 (2-3) :413-421
[10]   Sonochemical intercalation of preformed gold nanoparticles into multilayered clays [J].
Belova, Valentina ;
Moehwald, Helmuth ;
Schukin, Dmitry G. .
LANGMUIR, 2008, 24 (17) :9747-9753