Progress on Transition Metal-Catalyzed Asymmetric Allylic Alkylation Reaction of 1,3-Dicarbonyl Compounds

被引：9
作者：
Zheng, Nan [1 ,3 ]
Song, Wangze [2 ,3 ]
机构：
[1] Dalian Univ Technol, Sch Chem Engn, Dalian 116024, Peoples R China
[2] Dalian Univ Technol, Sch Pharmaceut Sci & Technol, Dalian 116024, Peoples R China
[3] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2017年 / 37卷 / 05期
关键词：
transition-metal catalysis; 1,3-dicarbonyl compounds; asymmetric allylic alkylation reaction; REGIOSELECTIVE DECARBOXYLATIVE ADDITION; ONE-POT SYNTHESIS; ENANTIOSELECTIVE CONSTRUCTION; BETA-KETOESTERS; CONFORMATIONAL PREFERENCES; NUCLEOPHILIC-ATTACK; BOND FORMATION; N; P LIGANDS; ALLYLATION; PD;
D O I：
10.6023/cjoc201702013
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Asymmetric allylic alkylation reaction of 1,3-dicarbonyl compounds is one of the most important methods for forming chiral carbon center. This review summarizes the progress on transition metal-catalyzed asymmetric allylic alkylation reaction of 1,3-dicarbonyl compounds. Different allylating reagents such as allylic esters, allylic alcohols, allylic halides, olefins, allenes and others for the synthesis of a-allyl substituted 1,3-dicarbonyl compounds are discussed.
引用
收藏
页码：1099 / 1110
页数：12
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