Diorganotelluride-Catalyzed Oxidation of Silanes to Silanols under Atmospheric Oxygen

被引：57
作者：
Okada, Yasunori [1 ]
Oba, Makoto [1 ]
Arai, Atsushi [1 ]
Tanaka, Kazuhito [1 ]
Nishiyama, Kozaburo [1 ]
Ando, Wataru [2 ]
机构：
[1] Tokai Univ, Dept Chem Mat, Shizuoka 4100395, Japan
[2] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058565, Japan
来源：
INORGANIC CHEMISTRY | 2010年 / 49卷 / 02期
关键词：
ASYMMETRIC SILICON; HETEROGENEOUS OXIDATION; HYDROLYTIC OXIDATION; OXIDIZING PROPERTIES; ORGANOSILANES; METHYLTRIOXORHENIUM; STEREOCHEMISTRY; CONVERSION; INSERTION; ALKENYLSILANOLS;
D O I：
10.1021/ic9022745
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Diorganotellurides efficiently catalyze the aerobic oxidation of organosilanes under photosensitized conditions to afford the corresponding silanols in excellent yield.
引用
收藏
页码：383 / 385
页数：3
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