Preparation of Cu2Sn1-x,GexS3 bulk single crystals by chemical vapor transport with iodine

被引：12

作者：

Fujita, Riki ^{[1
]}

Saito, Nobuo ^{[2
]}

Kosugi, Kenichiro ^{[3
]}

Tanaka, Kunihiko ^{[1
]}

机构：

[1] Nagaoka Univ Technol, Dept Elect Elect & Informat Engn, 1603-1 Kamitomioka, Nagaoka, Niigata 9402188, Japan

[2] Nagaoka Univ Technol, Dept Mat Sci & Technol, 1603-1 Kamitomioka, Nagaoka, Niigata 9402188, Japan

[3] Nagaoka Univ Technol, Ctr Integrated Technol Support, 1603-1 Kamitomioka, Nagaoka, Niigata 9402188, Japan

来源：

JOURNAL OF CRYSTAL GROWTH | 2018年 / 498卷

关键词：

Crystal structure; X-ray diffraction; Growth from vapo; Single crystal growth; Sulfides; CU(IN; GA)SE-2; SOLAR-CELLS; THIN-FILM; GE; SULFURIZATION; ABSORBER; GROWTH; SN;

D O I：

10.1016/j.jcrysgro.2018.06.031

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Bulk crystals of monoclinic Cu2Sn1-xGexS3 were prepared by chemical vapor transport with iodine. The samples were investigated using electron-probe microanalysis, transmission electron microscopy, Raman spectroscopy and X-ray diffraction (XRD). All of the samples had a Cu-rich and S-poor composition. As the Ge content increased, the XRD peaks shifted to higher angle, the Raman peaks shifted to higher wavenumber, and the lattice constants decreased. Selected-area electron diffraction patterns showed that the samples were single crystal and had a monoclinic structure.

引用

页码：258 / 262

页数：5

共 31 条

[1] Photoluminescence characterization of Cu2GeS3 bulk crystals [J].

Aihara, Naoya ;

Matsumoto, Yusuke ;

Tanaka, Kunihiko .

PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2017, 254 (06)

[2] Exciton luminescence from Cu2SnS3 bulk crystals [J].

Aihara, Naoya ;

Matsumoto, Yusuke ;

Tanaka, Kunihiko .

APPLIED PHYSICS LETTERS, 2016, 108 (09)

[3] Sulfurization temperature dependences of photovoltaic properties in Cu2SnS3-based thin-film solar cells [J].

Aihara, Naoya ;

Kanai, Ayaka ;

Kimura, Kazuki ;

Yamada, Manami ;

Toyonaga, Kotoba ;

Araki, Hideaki ;

Takeuchi, Akiko ;

Katagiri, Hironori .

JAPANESE JOURNAL OF APPLIED PHYSICS, 2014, 53 (05)

[4] Synthesis and characterization of Cu2Sn1-xGexS3 [J].

Araki, Hideaki ;

Yamano, Masaki ;

Nishida, Genki ;

Takeuchi, Akiko ;

Aihara, Naoya ;

Tanaka, Kunihiko .

PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 14 NO 6, 2017, 14 (06)

[5] Fabrication of Cu2GeS3-based thin film solar cells by sulfurization of Cu/Ge stacked precursors [J].

Araki, Hideaki ;

Chino, Kotaro ;

Kimura, Kazuki ;

Aihara, Naoya ;

Jimbo, Kazuo ;

Katagiri, Hironori .

JAPANESE JOURNAL OF APPLIED PHYSICS, 2014, 53 (05)

[6] Thin film solar cells based on the ternary compound Cu2SnS3 [J].

Berg, Dominik M. ;

Djemour, Rabie ;

Guetay, Levent ;

Zoppi, Guillaume ;

Siebentritt, Susanne ;

Dale, Phillip J. .

THIN SOLID FILMS, 2012, 520 (19) :6291-6294

[7] Raman analysis of monoclinic Cu2SnS3 thin films [J].

Berg, Dominik M. ;

Djemour, Rabie ;

Guetay, Levent ;

Siebentritt, Susanne ;

Dale, Phillip J. ;

Fontane, Xavier ;

Izquierdo-Roca, Victor ;

Perez-Rodriguez, Alejandro .

APPLIED PHYSICS LETTERS, 2012, 100 (19)

[8] 13.3% efficient solution deposited Cu(In,Ga)Se2 solar cells processed with different sodium salt sources [J].

Berner, Ulrich ;

Colombara, Diego ;

de Wild, Jessica ;

Robert, Erika V. C. ;

Schuetze, Martin ;

Hergert, Frank ;

Valle, Nathalie ;

Widenmeyer, Markus ;

Dale, Phillip J. .

PROGRESS IN PHOTOVOLTAICS, 2016, 24 (06) :749-759

[9] Introduction of Na into Cu2SnS3 thin film for improvement of its photovoltaic performances [J].

Chantana, Jakapan ;

Suzuki, Koichi ;

Minemoto, Takashi .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2017, 168 :207-213

[10] Preparation of Cu2SnS3 Thin Films by Sulfurization of Cu/Sn Stacked Precursors [J].

Chino, Kotaro ;

Koike, Junpei ;

Eguchi, Shinya ;

Araki, Hideaki ;

Nakamura, Ryota ;

Jimbo, Kazuo ;

Katagiri, Hironori .

JAPANESE JOURNAL OF APPLIED PHYSICS, 2012, 51 (10)

← 1 2 3 4 →