Gels as a soft matter route to conducting nanostructured organic and composite materials

被引:61
作者
Amabilino, David B. [1 ]
Puigmarti-Luis, Josep [1 ]
机构
[1] CSIC, Inst Ciencia Mat Barcelona, Bellaterra 08193, Spain
关键词
DISCOTIC LIQUID-CRYSTALS; LANGMUIR-BLODGETT-FILMS; SELF-ASSEMBLED FIBERS; TETRATHIAFULVALENE DERIVATIVES; SUPRAMOLECULAR ELECTRONICS; MOLECULAR NANOWIRES; BUILDING-BLOCKS; TTF DERIVATIVES; PHASE MATERIALS; ORGANOGELATOR;
D O I
10.1039/b923618j
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The preparation of supramolecular nanowires capable of conducting electricity can be achieved via the gel state. These wires, which range in width from a few to several tens of nanometres, are connected in a network-characteristic of organogels-which can provide bulk conducting materials thanks to close contacts between the fibres. They are easy to process and do not rely on the crystalline state for their properties, and importantly do not depend on the surface to which they are applied. The gel state can also be used as a route for the preparation of nanocomposite materials, whose structure can be controlled by modifying the compatibility between the components. In addition, they contain nanowires which, provided their location could be controlled, may prove of utility in nanoscale devices.
引用
收藏
页码:1605 / 1612
页数:8
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