Hydrothermal synthesis and characterization of layered vanadium phosphite:: [HN(C2H4)3N][(VO)2(HPO3)2(OH)(H2O)]•H2O

被引：27

作者：

Shi, Z ^{[1
]}

Zhang, D ^{[1
]}

Li, GH ^{[1
]}

Wang, L ^{[1
]}

Lu, XY ^{[1
]}

Hua, J ^{[1
]}

Feng, SH ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2003年 / 172卷 / 02期

基金：

中国国家自然科学基金;

关键词：

hydrothermal synthesis; vanadium phosphite; layered structure;

D O I：

10.1016/S0022-4596(03)00037-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel compound, [HN(C2H4)(3)N][(VO)(2)(HPO3)(2)(OH)(H2O)] (.) H2O, was hydrothermally synthesized and characterized by single crystal X-ray diffraction. This compound crystallizes in the monoclinic system with the space group C2/c and cell parameters a = 11.0753(3) Angstrom, b = 17.8265(6) Angstrom, c = 16.5229(5) Angstrom, and beta = 92.362(2)degrees. The structure of the compound consists of vanadium phosphite layers which are built up from the infinite one-dimensional chains of [(VO)(H2O)(HPO3)(2)](2-) of octahedral VO5(H2O) and pseudo pyramidal [HPO3], and bridging binuclear fragments of [VO(OH)](2). Thermogravimetric analysis and magnetic susceptibility data for this compound are given. (C) 2003 Elsevier Science (USA). All rights reserved.

引用

页码：464 / 470

页数：7

共 26 条

[1] Synthesis, structure, and magnetism of CN3H6•VO(H2O)(HPO4)(H2PO4)•H2O, a new guanidinium vanadium(IV) phosphate
Bircsak, Z
Hall, AK
Harrison, WTA
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 1999, 142 (01) : 168 - 173
[2] HYDROTHERMAL SYNTHESIS AND CHARACTERIZATION OF 2- AND 3-DIMENSIONAL SOLIDS OF THE OXOVANADIUM(IV)-PHOSPHITE SYSTEM - THE STRUCTURES OF [HN(ME)(CH2CH2)(2)N(ME)H]-[(VO)(4)(OH)(2)(HPO3)(4)], [H2N(CH2CH2)(2)NH2][(VO)(3)(HPO3)(4)(H2O)(2)], AND [VO(HPO3)(H2O)]
BONAVIA, G
DEBORD, J
HAUSHALTER, RC
ROSE, D
ZUBIETA, J
[J]. CHEMISTRY OF MATERIALS, 1995, 7 (11) : 1995 - &
[3] BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE
BROWN, ID
ALTERMATT, D
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG): : 244 - 247
[4] EMPIRICAL BOND-STRENGTH BOND-LENGTH CURVES FOR OXIDES
BROWN, ID
SHANNON, RD
[J]. ACTA CRYSTALLOGRAPHICA SECTION A, 1973, A 29 (MAY1): : 266 - 282
[5] Cheetham AK, 1999, ANGEW CHEM INT EDIT, V38, P3268, DOI 10.1002/(SICI)1521-3773(19991115)38:22<3268::AID-ANIE3268>3.0.CO
[6] 2-U
[7] Hydrothermal synthesis and characterization of two mixed valence piperazine-vanadium phosphates:: (C4H12N2)(H3O)[(VOPO4)4(H2O)H2PO4]•3H2O and (C4H12N2)[(VO)(VO2)2(H2O)(PO4)2]
Do, J
Bontchev, RP
Jacobson, AJ
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 2000, 154 (02) : 514 - 523
[8] *FED I MAT RES TES, 2000, POWD WIND VERS 2 4
[9] Microporous solids:: From organically templated inorganic skeletons to hybrid frameworks ... ecumenism in chemistry
Férey, G
[J]. CHEMISTRY OF MATERIALS, 2001, 13 (10) : 3084 - 3098
[10] Hydrothermal synthesis of a new layered inorganic-organic hybrid cobalt(II) phosphite:: (C2H10N2[Co3(HPO3)4] crystal structure and spectroscopic and magnetic properties
Fernández, S
Pizarro, JL
Mesa, JL
Lezama, L
Arriortua, MI
Rojo, T
[J]. INTERNATIONAL JOURNAL OF INORGANIC MATERIALS, 2001, 3 (4-5): : 331 - 336

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