Intercalation of acrylate anions into the galleries of Zn-Al layered double hydroxide

被引：31

作者：

Aguzzi, Alessia

Ambrogi, Valeria

Costantino, Umberto

Marmottini, Fabio

机构：

[1] CEMIN, Dipartimento Chim, I-06123 Perugia, Italy

[2] Dipartimento Chim & Tecnol Farmaco, I-06123 Perugia, Italy

[3] Dipartimento Ingn Civile & Ambientale, I-06125 Perugia, Italy

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 2007年 / 68卷 / 5-6期

关键词：

x-ray diffraction; oxides; nanostructures; polymers; thermogravimetric analysis (TGA);

D O I：

10.1016/j.jpcs.2006.12.031

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Acrylate and methacrylate anions containing double bond and carboxylic groups, were intercalated in the interlayer region of a layered double hydroxide of formula: [Zn0.66Al0.34(OH)(2)](NO3)(0.34) 0.62H(2)O. The intercalation compounds obtained have been characterized for their chemical composition and with different instrumental techniques (X-ray powder diffraction, thermal analysis, FT-IR absorption spectroscopy, electron scanning microscopy). Furthermore, they have been used to carry out a preliminary study concerning the in situ polymerization of the intercalated acrylate and methacrylate ions to obtain new interstratified inorgano-organic hybrid materials. (C) 2007 Elsevier Ltd. All rights reserved.

引用

页码：808 / 812

页数：5

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