Synthesis and structural analysis of (μ-SCH2CH2CH2S-μ)Fe2(CO)5(2-C5H4NPPh2)

被引：1

作者：

Liu, Xu-Feng ^{[1
]}

机构：

[1] Ningbo Univ Technol, Dept Chem Engn, Ctr Anal & Testing, Ningbo 315016, Zhejiang, Peoples R China

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2016年 / 624卷 / 01期

关键词：

synthesis; diiron dithiolate; crystal structure; Carbonyl substitution; DIIRON PROPANEDITHIOLATE COMPLEXES; PROTON-REDUCTION CATALYSTS; IRON-ONLY HYDROGENASE; CRYSTAL-STRUCTURES; ELECTROCHEMICAL PROPERTIES; AZADITHIOLATE COMPLEXES; DIPHOSPHINE LIGANDS; ACTIVE-SITE; MODEL; ISOMERS;

D O I：

10.1080/15421406.2015.1038028

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of (mu-SCH2CH2CH2S-mu)Fe-2(CO)(6) with equimolar 2-C5H4NPPh2 in the presence of Me3NO center dot 2H(2)O in CH2Cl2/MeCN solutions gave the title complex (mu-SCH2CH2CH2S-mu)Fe-2(CO)(5)(2-C5H4NPPh2) in 76% yield. The title complex was characterized by spectroscopy as well as by single crystal X-ray diffraction analysis. The molecular structure consists of a butterfly [Fe2S2] cluster with propane, five carbonyls, and 2-C5H4NPPh2. In the crystal packing diagram, intermolecular C-H center dot center dot center dot O hydrogen bonds between phenyl and carbonyl groups stabilize the solid state.

引用

页码：257 / 261

页数：5

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