Specific surface area of spinel oxides by Zn2+-ion adsorption (ZIA). Case of dry and hydrous Co3O4: feasibility and limitation

被引：5

作者：

Chartier, P

Hitz, C

Koenig, JF

机构：

[1] Lab. d'Electrochimie Chim.-Phys. C., URA CNRS 405, Université Louis Pasteur, 67000 Strasbourg

来源：

ELECTROCHIMICA ACTA | 1997年 / 42卷 / 23-24期

关键词：

real surface area; hydrous oxides; spinels; oxide electrodes;

D O I：

10.1016/S0013-4686(97)00022-4

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Co3O4 powders prepared by thermal decomposition of nitrate (TDN) and by precipitation in aqueous solution (PAS) have been investigated in relation with the zinc-ion adsorption (ZIA) method of in situ measurement of specific areas at the solid-liquid interface. The ZIA method seems feasible with dry TDN powders, while high solubility and cation exchanges hinder the method with hydrous PAS powders. The ZIA surface areas of dry Co3O4 are approximately 1/2 the BET surface areas.

引用

页码：3471 / 3475

页数：5

共 18 条

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