Kinetic study of coal steam and CO2 gasification: A new method to reduce interparticle diffusion

The effect of coal bed thickness was studied and compared between steam and CO2 gasification. Despite using small amounts of coal sample, both gasifying agents' kinetics, i.e., steam and CO2, proved to be affected by bulk and interparticle diffusion. Comparison between the gasifying agents indicates that mass transfer effects are minimized when the raw material layer and particle size are smaller than 0.14 mm and 90 mu m, respectively. In addition to mass transfer limitations, studies have confirmed that the reported maximum reaction rate is a consequence of the gas switching between inert and reaction gas during steam gasification; therefore, the time to replace the reaction medium cannot be considered as part of the kinetic analysis or taken into account in the kinetic model that represents the reaction mechanism. Nevertheless, it is not appropriate to use steam alone during pyrolysis and gasification in kinetic studies, since these two reactions overlap in the same temperature reaction range. An alternative method to overcoming these restrictions is proposed in this study. The present study demonstrates a consistent method to perform gasification in the chemically controlled temperature range between 750 degrees C and 900 degrees C. In addition, the apparent activation energy is estimated independent of the kinetic model. (C) 2015 Elsevier Ltd. All rights reserved.