Fabrication of titanium bipolar plates by rubber forming and performance of single cell using TiN-coated titanium bipolar plates

被引:74
作者
Jin, Chul Kyu [1 ]
Jeong, Min Geun [1 ]
Kang, Chung Gil [2 ]
机构
[1] Pusan Natl Univ, Grad Sch, Precis Mfg Syst Div, Pusan 609735, South Korea
[2] Pusan Natl Univ, Sch Mech Engn, Engn Res Ctr Net Shape & Die Mfg, Pusan 609735, South Korea
基金
新加坡国家研究基金会;
关键词
Rubber forming; Draft angle; Bipolar plates; Titanium; TiN coating; Performance; MEMBRANE FUEL-CELLS; FORMABILITY;
D O I
10.1016/j.ijhydene.2014.03.013
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this study, a rubber forming method is used to fabricate titanium bipolar plates for proton exchange membrane fuel cells. A titanium blank with a thickness of 0.1 mm is compressed using a stamping mold equipped with a 200-ton hydraulic press to fabricate bipolar plates. A forming experiment is carried out by changing different parameters such as the punch velocity, punch pressure, rubber thickness, rubber hardness, and draft angle of the channel. The optimum forming conditions are found to be a rubber thickness of 10 mm, rubber hardness equivalent to that of Shore A 20, punch velocity of 30 mm s(-1), punch pressure of 55 MPa, and punch draft angle of 30 degrees. The fabricated titanium bipolar plate is coated with a TiN layer. A single cell with a TiN-coated titanium bipolar plate is examined and compared to those with uncoated titanium and graphite bipolar plates. The initial performances (in terms of current densities) of the single cells with the uncoated titanium, TiN-coated titanium, and graphite bipolar plates are 396, 799, and 1160 mA cm(-2), respectively, at a cell voltage of 0.6 V. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:21480 / 21488
页数:9
相关论文
共 15 条
[1]   Bipolar plates for PEM fuel cells: A review [J].
Hermann, A ;
Chaudhuri, T ;
Spagnol, P .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2005, 30 (12) :1297-1302
[2]   Studies on the fabrication of metallic bipolar plates-Using micro electrical discharge machining milling [J].
Hung, Jung-Chung ;
Yang, Tzu-Chun ;
Li, Kuo-Chou .
JOURNAL OF POWER SOURCES, 2011, 196 (04) :2070-2074
[3]   Fabrication by vacuum die casting and simulation of aluminum bipolar plates with micro-channels on both sides for proton exchange membrane (PEM) fuel cells [J].
Jin, Chul Kyu ;
Kang, Chung Gil .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (02) :1661-1676
[4]   Fabrication process analysis and experimental verification for aluminum bipolar plates in fuel cells by vacuum die-casting [J].
Jin, Chul Kyu ;
Kang, Chung Gil .
JOURNAL OF POWER SOURCES, 2011, 196 (20) :8241-8249
[5]   Effect of progressive forming process and processing variables on the formability of aluminium bipolar plate with microchannel [J].
Kwon, Hae-June ;
Jeon, Yong-Phil ;
Kang, Chung-Gil .
INTERNATIONAL JOURNAL OF ADVANCED MANUFACTURING TECHNOLOGY, 2013, 64 (5-8) :681-694
[6]   Fabrication of aluminum 1050 micro-channel proton exchange membrane fuel cell bipolar plate using rubber-pad-forming process [J].
Lim, S. S. ;
Kim, Y. T. ;
Kang, C. G. .
INTERNATIONAL JOURNAL OF ADVANCED MANUFACTURING TECHNOLOGY, 2013, 65 (1-4) :231-238
[7]   Fabrication of metallic bipolar plate for proton exchange membrane fuel cells by rubber pad forming [J].
Liu, Yanxiong ;
Hua, Lin .
JOURNAL OF POWER SOURCES, 2010, 195 (11) :3529-3535
[8]   Effect of manufacturing processes on formability and surface topography of proton exchange membrane fuel cell metallic bipolar plates [J].
Mahabunphachai, Sasawat ;
Cora, Oemer Necati ;
Koc, Muammer .
JOURNAL OF POWER SOURCES, 2010, 195 (16) :5269-5277
[9]   Bipolar plates for PEM fuel cells [J].
Middelman, E ;
Kout, W ;
Vogelaar, B ;
Lenssen, J ;
de Waal, E .
JOURNAL OF POWER SOURCES, 2003, 118 (1-2) :44-46
[10]   Analysis of the polymer composite bipolar plate properties on the performance of PEMFC (polymer electrolyte membrane fuel cells) by RSM (response surface methodology) [J].
San, Fatma Gul Boyaci ;
Isik-Gulsac, Isil ;
Okur, Osman .
ENERGY, 2013, 55 :1067-1075