Effect of end-group modification on the adsorption of poly(ethylene oxide)-b-poly(butylene oxide) diblock copolymers at the solid-liquid interface

被引：5
|
作者：
Siddiq, Mohammad [1 ]
Liu, Guangming [2 ]
Zhang, Guangzhao [2 ]
Khan, Abbas [1 ]
Budd, Peter M. [3 ]
机构：
[1] Quaid I Azam Univ, Dept Chem, Islamabad, Pakistan
[2] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Dept Chem Phys, Hefei, Anhui, Peoples R China
[3] Univ Manchester, Sch Chem, Manchester, Lancs, England
来源：
POLYMER BULLETIN | 2010年 / 65卷 / 05期
关键词：
Diblock copolymers; Adsorption; Quartz crystal microbalance; Solid-liquid interface; Multilayer structure; STRUCTURE-DIRECTING AGENTS; MESOPOROUS SILICA; SURFACE-ROUGHNESS; BLOCK-COPOLYMERS; COMPLEXES; MICELLES; WATER;
D O I：
10.1007/s00289-010-0303-0
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The adsorption of poly(ethylene oxide)-b-poly(butylene oxide) diblock copolymers at the solid-liquid interface was studied using a quartz crystal microbalance with dissipation monitoring (QCM-D). The effect of modifying the end group of the hydrophilic block was investigated by comparing the behaviour of trimethylammonium- and dimethylamino-tipped copolymers, designated as TE (m) B (n) and DE (m) B (n) , respectively. For adsorption from aqueous solution onto a gold surface, results for DE49B22 were similar to those of the T-analogue, but for DE80B34 adsorbed amounts were substantially higher, and for DE27B25 enormously higher, than for the T-analogue. It is suggested that very high levels of adsorption are associated with the formation of a multilayer structure.
引用
收藏
页码：521 / 531
页数：11
相关论文
共 50 条
  • [21] Interfacial behavior of poly(ethylene oxide)-b-poly(ε-caprolactone) copolymers at the air-water interface
    Denoncourt, Kristina M.
    Joncheray, Thomas J.
    Meier, Michael A. R.
    Schubert, Ulrich S.
    Duran, Randolph S.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
  • [22] Effect of end group on the micelle properties of diblock copolymers of ethylene oxide and 1,2-butylene oxide
    Kelarakis, A
    Mai, SM
    Havredaki, V
    Nace, VM
    Booth, C
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2001, 3 (18) : 4037 - 4043
  • [23] Influence of end-group modification on interaction of amphiphilic poly(oxyethylene)-b-poly(oxybutylene) block copolymers with ionic surfactants
    Iram Bibi
    Naveed Ahmed
    Syed Waqar Hussain Shah
    Mohsin Nawaz
    Abdur Rab
    Robina Naz
    Luqman Ali Shah
    Journal of Polymer Research, 2018, 25
  • [24] ! Influence of end-group modification on interaction of amphiphilic poly(oxyethylene)-b-poly(oxybutylene) block copolymers with ionic surfactants
    Bibi, Iram
    Ahmed, Naveed
    Shah, Syed Waqar Hussain
    Nawaz, Mohsin
    Rab, Abdur
    Naz, Robina
    Shah, Luqman Ali
    JOURNAL OF POLYMER RESEARCH, 2018, 25 (10)
  • [25] Cellular internalization of poly(ethylene oxide)-b-poly(ε-caprolactone) diblock copolymer micelles
    Luo, LB
    Tam, J
    Maysinger, D
    Eisenberg, A
    BIOCONJUGATE CHEMISTRY, 2002, 13 (06) : 1259 - 1265
  • [26] Crazing Mechanism and Physical Aging of Poly(lactide) Toughened with Poly(ethylene oxide)-block-poly(butylene oxide) Diblock Copolymers
    McCutcheon, Charles J.
    Zhao, Boran
    Jin, Kailong
    Bates, Frank S.
    Ellison, Christopher J.
    MACROMOLECULES, 2020, 53 (22) : 10163 - 10178
  • [27] Nanoparticles built of cross-linked heterotelechelic, amphiphilic poly(dimethylsiloxane)-b-poly(ethylene oxide) diblock copolymers
    Rheingans, O
    Hugenberg, N
    Harris, JR
    Fischer, K
    Maskos, M
    MACROMOLECULES, 2000, 33 (13) : 4780 - 4790
  • [28] Confined lamella formation in crystalline-crystalline poly(ethylene oxide)-b-poly(E⟩-caprolactone) diblock copolymers
    Xue, Fei-fei
    Chen, Xue-si
    An, Li-jia
    Funari, Sergio S.
    Jiang, Shi-chun
    CHINESE JOURNAL OF POLYMER SCIENCE, 2013, 31 (09) : 1260 - 1270
  • [29] Liquid-Liquid Phase Equilibrium of Triblock Copolymer F68, Poly(ethylene oxide)-b-poly(propylene oxide)-b-poly(ethylene oxide), with Sulfate Salts
    Martins, Joao Paulo
    Hespanhol da Silva, Maria do Carmo
    Mendes da Silva, Luis Henrique
    Arrighi Senra, Tonimar Domiciano
    Dias Ferreira, Guilherme Max
    dos Reis Coimbra, Jane Selia
    Minim, Luis Antonio
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2010, 55 (04): : 1618 - 1622
  • [30] Diblock Copolymers of Poly(ethylene oxide)-b-poly(propylene oxide) Stabilize a Blood-Brain Barrier Model under Oxidative Stress
    Mondkar, Pranati P.
    Seo, Hannah S.
    Lodge, Timothy P.
    Azarin, Samira M.
    MOLECULAR PHARMACEUTICS, 2024, 21 (11) : 5646 - 5660
12345