Unusual KMnO4 oxidation product of β-ionone

被引：0

作者：

Kamat, Shrivallabh P. ^{[1
]}

D'Souza, Asha M.

Paknikar, Shashikumar K.

Bhadbhade, Mohan M.

Gonnade, Rajesh G.

机构：

[1] Goa Univ, Dept Chem, Taleigao Plateau 403206, Goa, India

[2] Kundai Ind Estate, Siddharth Chem, Kundai 403115, Goa, India

[3] Natl Chem Lab, Ctr Mat Characterizat, Pune 411008, Maharashtra, India

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY | 2007年 / 46卷 / 06期

关键词：

beta-ionone; KMnO4; oxidation; hydroxyionolactone; bromolactone; crystal structure; X-ray diffraction;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

KMnO4 oxidation of P-ionone has been reinvestigated. The structure proposed for the hydroxyionolactone 3 obtained in this reaction is supported by MS, UV, IR, H-1 and C-13 NMR data and further confirmed by single crystal X-ray diffraction studies of the brornolactone 8.

引用

页码：1038 / 1041

页数：4

共 8 条

[1] DITERPENE CHEMISTRY .2. PREFERENTIAL OXIDATION OF VINYL GROUPS OF PIMARIC AND SANDARACOPIMARIC ACIDS [J].

APSIMON, JW ;

CHAU, ASY ;

CRAIG, WG ;

KREHM, H .

CANADIAN JOURNAL OF CHEMISTRY, 1967, 45 (13) :1439-&

[2] CONSTITUTION OF AN OXIDATION PRODUCT OF BETA-IONONE [J].

BROOKS, CJ ;

MAGRILL, DS ;

EGLINTON, G .

JOURNAL OF THE CHEMICAL SOCIETY, 1961, (JAN) :308-&

[3]

Johnson C. K., 1976, ORNL5138 ORTEP

[4]

RODD, 1953, CHEM CARBON COMPOUND, V2, P503

[5] Bromination of acetanilide [J].

Schatz, PF .

JOURNAL OF CHEMICAL EDUCATION, 1996, 73 (03) :267-267

[6]

Sheldrick G. M., 1997, SHELXS 97 SHELXS 97

[7]

SIMONSEN JL, 1953, TERPENES, V1, P128

[8]

TIEMAN, 1898, BER, V31, P857

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