Periodate activation for degradation of organic contaminants: Processes, performance and mechanism

被引：80

作者：

Li, Renxin ^{[1
]}

Wang, Jingquan ^{[1
]}

Wu, Han ^{[1
]}

Zhu, Zhuoyu ^{[1
]}

Guo, Hongguang ^{[1
]}

机构：

[1] Sichuan Univ, Coll Architecture & Environm, MOE Key Lab Deep Earth Sci & Engn, Chengdu 610065, Peoples R China

来源：

SEPARATION AND PURIFICATION TECHNOLOGY | 2022年 / 292卷

基金：

中国国家自然科学基金;

关键词：

Periodate activation; Contaminants; Degradation performance; Mechanism; Factors; ENHANCED PHOTOCATALYTIC ACTIVITY; DOPED ZNO NANOPARTICLES; ACID ORANGE 7; WASTE-WATER; SONOCATALYTIC DEGRADATION; SONOCHEMICAL DEGRADATION; INORGANIC OXIDANTS; AQUEOUS-SOLUTION; PHOTOACTIVATED PERIODATE; REACTION PARAMETERS;

D O I：

10.1016/j.seppur.2022.120928

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Periodate (IO4-) activation in environmental remediation has aroused tremendous attention, due to its high oxidative potential for the degradation of contaminants and fair stability in the water. In this review, we systematically summarized the periodate-based AOPs, where the activating methods were categorized into three types: (1) homogeneous activation (Mn2+/IO4-, Fe(II)/IO4-, H2O2/IO4-, HA/IO4-, UV or ultrasound/IO4-); (2) heterogeneous activation (iron-based materials/IO4-, TiO2-based materials/IO4-, WO3/IO4-, carbon materials/IO4-, zinc-based materials/IO4-, and other metal oxides); (3) direct activation (freeze activation, heat activation, alkali activation). This review mainly summarized the effective pH range of the processes, production of reactive species, and degradation performance of target pollutants. Relevant reaction mechanisms were further elaborated, and the main active intermediates in the process of activating periodate as well as the specific paths of their generation were summarized. Finally, the challenges and prospects in the periodate-applied field were discussed. This review comprehensively summarized the processes of activating periodate to degrade pollutants, analyzed the controversy involved in the reaction mechanism, and provided a direction for the future research of periodate.

引用

页数：15

共 142 条

[1] A novel UV and visible light driven photocatalyst AgIO4/ZnO nanoparticles with highly enhanced photocatalytic performance for removal of rhodamine B and indigo carmine dyes [J].