Correlation trends in the hyperfine structure for Rb, Cs, and Fr, and high-accuracy predictions for hyperfine constants

被引:16
作者
Grunefeld, S. J. [1 ]
Roberts, B. M. [1 ]
Ginges, J. S. M. [1 ]
机构
[1] Univ Queensland, Sch Math & Phys, Brisbane, Qld 4072, Australia
基金
澳大利亚研究理事会;
关键词
EXCITED S-STATES; FRANCIUM; RUBIDIUM; SPECTROSCOPY; TRANSITION; TABLE; ATOMS;
D O I
10.1103/PhysRevA.100.042506
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
We perform high-precision calculations of the hyperfine structure for nS(1/2) and nP(1/2) states of the alkali-metal atoms Rb, Cs, and Fr across the principal quantum number n and study the trend in the size of the correlations. Our calculations are performed in the all-orders correlation potential method. We demonstrate that the relative correlation corrections fall off quickly with n and tend towards constant and nonzero values for highly excited states. This trend is supported by experiments, and we utilize the smooth dependence on n to make high-accuracy predictions of the hyperfine constants, with uncertainties to within 0.1% for most considered S-1/2 states of Rb and Cs.
引用
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页数:10
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