Oxaphospholene and oxaphosphinene heterocycles via RCM using unsymmetrical phosphonates or functional phosphinates

被引：44

作者：

Fourgeaud, Pierre ^{[1
]}

Midrier, Camille ^{[1
]}

Vors, Jean-Pierre ^{[2
]}

Volle, Jean-Noel ^{[1
]}

Pirat, Jean-Luc ^{[1
]}

Virieux, David ^{[1
]}

机构：

[1] ENSCM, Inst Charles Gerhardt, UMR5253, AM2N, F-34296 Montpellier 5, France

[2] Bayer CropSci, F-69263 Lyon 09, France

来源：

TETRAHEDRON | 2010年 / 66卷 / 03期

关键词：

RING-CLOSING METATHESIS; OLEFIN METATHESIS; NATURAL-PRODUCTS; PHOSPHORUS; ANALOGS; OXIDES;

D O I：

10.1016/j.tet.2009.11.049

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

New phosphorus heterocycles were synthesized using RCM reaction. They were prepared from unsymmetrical or polyfunctional insaturated precursor in 50 to 87% yields solving the problem of possible competitive side reactions. In parallel hydroxyphosphinate scaffolds represent a versatile starting material and could be of great interest for the synthesis of phosphosugar libraries. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：758 / 764

页数：7

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