Self-Assembly of 1D/2D Hybrid Nanostructures Consisting of a Cd(II) Coordination Polymer and NiAl-Layered Double Hydroxides

被引:8
作者
Abellan, Gonzalo [1 ,2 ,3 ,4 ]
Amo-Ochoa, Pilar [5 ,6 ]
Fierro, Jose Luis G. [7 ]
Ribera, Antonio [1 ]
Coronado, Eugenio [1 ]
Zamora, Felix [5 ,6 ,8 ]
机构
[1] Univ Valencia, Inst Ciencia Mol, Catedrat Jose Beltran 2, Valencia 46980, Spain
[2] Univ Erlangen Nurnberg, Dept Chem & Pharm, Henkestr 42, D-91054 Erlangen, Germany
[3] Univ Erlangen Nurnberg, Inst Adv Mat & Proc ZMP, Henkestr 42, D-91054 Erlangen, Germany
[4] Dr Mack Str 81, D-90762 Furth, Germany
[5] Univ Autonoma Madrid, Dept Quim Inorgan, E-28049 Madrid, Spain
[6] Univ Autonoma Madrid, Condensed Matter Phys Ctr IFIMAC, E-28049 Madrid, Spain
[7] Inst Catalisis & Petroleoquim, Madrid 28049, Spain
[8] Inst Madrileno Estudios Avanzados Nanociencia IMD, Madrid 28049, Spain
关键词
hybrid materials; layered double hydroxides; coordination polymers; magnetic properties; layered compounds; PROBE MICROSCOPY CHARACTERIZATION; CHAINS; 6-MERCAPTOPURINE; INTERCALATION; MAGNETISM; SURFACES; COMPLEX;
D O I
10.3390/polym8010005
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The preparation and characterization of a novel hybrid material based on the combination of a 2D-layered double hydroxide (LDH) nanosheets and a 1D-coordination polymer (1D-CP) has been achieved through a simple mixture of suspensions of both building blocks via an exfoliation/restacking approach. The hybrid material has been thoroughly characterized demonstrating that the 1D-CP moieties are intercalated as well as adsorbed on the surface of the LDH, giving rise to a layered assembly with the coexistence of the functionalities of their initial constituents. This hybrid represents the first example of the assembly of 1D/2D nanomaterials combining LDH with CP and opens the door for a plethora of different functional hybrid systems.
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页数:13
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