Crystal structure and enantiomeric layer disorder of a copper(I) nitrate π-cooramation compound

被引：3

作者：

Kowalska, Dorota A. ^{[1
]}

Kinzhybalo, Vasyl ^{[1
]}

Slyvka, Yuriy, I ^{[2
]}

Wolcyrz, Marek ^{[1
]}

机构：

[1] Polish Acad Sci, Inst Low Temp & Struct Res, Okolna 2, PL-50422 Wroclaw, Poland

[2] Ivan Franko Natl Univ Lviv, Dept Inorgan Chem, Kyryla & Mefodiya Str 6, UA-79005 Lvov, Ukraine

来源：

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS | 2021年 / 77卷

关键词：

tetrazole; copper(I); pi-coordination compound; crystal structure; X-ray diffuse scattering; local structure; DIFFUSE-SCATTERING; LIGAND SYNTHESIS; COMPLEX; ETHYLENE; AZIRIDINATION;

D O I：

10.1107/S2052520621001244

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The novel pi-coordination compound [Cu-I(m-dmphast)NO3], where m-dmphast = 5-(allylthio)-1-(3,5-dimethylphenyl)-1H-tetrazole, is characterized using single-crystal X-ray diffraction and crystallizes in a noncentrosymmetric space group. Additionally, for the first time in this group of materials, the streaks of X-ray diffuse scattering in the reciprocal space sections were observed and described. This gave the possibility for a deeper insight into the local structure of the title compound. The conjecture about the origin of diffuse scattering was derived from average structure solution. It was then confirmed using the local structure modelling. The extended [Cu(m-dmphast)NO3](infinity) chains, connected by weak interactions, produce layers which can exist in two enantiomeric forms, one of which predominates.

引用

页码：241 / 248

页数：8

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