Effect of Support Materials on the Selective Methanation of CO over Ru Catalysts

被引:38
作者
Urasaki, Kohei [1 ]
Endo, Ken-ichiro [1 ]
Takahiro, Tomoki [1 ]
Kikuchi, Ryuji [2 ]
Kojima, Toshinori [1 ]
Satokawa, Shigeo [1 ]
机构
[1] Seikei Univ, Fac Sci & Technol, Dept Mat & Life Sci, Musashino, Tokyo, Japan
[2] Univ Tokyo, Fac Engn, Dept Chem Syst Engn, Bunkyo Ku, Tokyo 113, Japan
关键词
Selective methanation; Ruthenium catalyst; Reformate gas; Support material; PREFERENTIAL OXIDATION; CARBON-MONOXIDE; HYDROGEN; GAS; REMOVAL; OXIDES;
D O I
10.1007/s11244-010-9509-5
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Selective methanation of CO in the reformate gas (CO/CO2/H-2/H2O = 0.175/17.9/70.9/11.1) proceeded over Ru catalysts supported on metal oxides and zeolites. CO was selectively methanated at wide temperature ranges (200-275 A degrees C) over Ru/gamma-Al2O3, Ru/TiO2 Ru/H-Y and Ru/H-beta catalysts. Higher Ru contents in Ru/gamma-Al2O3 improved the selective CO methanation rate.
引用
收藏
页码:707 / 711
页数:5
相关论文
共 50 条
  • [31] High Selectivity of Supported Ru Catalysts in the Selective CO Methanation-Water Makes the Difference
    Abdel-Mageed, Ali M.
    Eckle, Stephan
    Behm, R. Juergen
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (27) : 8672 - 8675
  • [32] Performance Intensification of CO2 Methanation by Co-Feeding Oxygen Over Various Ru-Based Catalysts
    Fukuhara, Choji
    Hirata, Nozomu
    Ozaki, Ren
    Watanabe, Ryo
    JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 2023, 56 (01)
  • [33] Methanation of CO, CO2 and selective methanation of CO, in mixtures of CO and CO2, over ruthenium carbon nanofibers catalysts
    Jimenez, Vicente
    Sanchez, Paula
    Panagiotopoulou, Paraskevi
    Luis Valverde, Jose
    Romero, Amaya
    APPLIED CATALYSIS A-GENERAL, 2010, 390 (1-2) : 35 - 44
  • [34] Influence of the catalyst loading on the activity and the CO selectivity of supported Ru catalysts in the selective methanation of CO in CO2 containing feed gases
    Eckle, Stephan
    Augustin, Matthias
    Anfang, Hans-Georg
    Behm, R. Juergen
    CATALYSIS TODAY, 2012, 181 (01) : 40 - 51
  • [35] The Effect of the Ruthenium Crystallite Size on the Activity of Ru/Carbon Systems in CO Methanation
    Truszkiewicz, Elzbieta
    Zegadlo, Kacper
    Wojda, Damian
    Mierzwa, Boguslaw
    Kepinski, Leszek
    TOPICS IN CATALYSIS, 2017, 60 (17-18) : 1299 - 1305
  • [36] Highly selective CO methanation over amorphous Ni-Ru-B/ZrO2 catalyst
    Liu, Qi Hai
    Dong, Xin Fa
    Lin, Wei Ming
    CHINESE CHEMICAL LETTERS, 2009, 20 (08) : 889 - 892
  • [37] CO selective methanation in H2-rich gas for fuel cell application: Microchannel reactor performance with Ru-based catalysts
    Galletti, C.
    Specchia, S.
    Specchia, V.
    CHEMICAL ENGINEERING JOURNAL, 2011, 167 (2-3) : 616 - 621
  • [38] Effect of the nature of the support, operating and pretreatment conditions on the catalytic performance of supported Ni catalysts for the selective methanation of CO
    Kokka, Aliki
    Ramantani, Theodora
    Petala, Athanasia
    Panagiotopoulou, Paraskevi
    CATALYSIS TODAY, 2020, 355 : 832 - 843
  • [39] Effect of noble metal addition over active Ru/TiO2 catalyst for CO selective methanation from H2 rich- streams
    Bobadilla, L. F.
    Munoz-Murillo, A.
    Gandara-Loe, J.
    Perez, A.
    Laguna, O. H.
    Martinez, T. L. M.
    Penkova, A.
    Centeno, M. A.
    Odriozola, J. A.
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2023, 48 (64) : 25065 - 25074
  • [40] CO2 Methanation over Supported Ru/Al2O3 Catalysts: Mechanistic Studies by In situ Infrared Spectroscopy
    Zheng, Jian
    Wang, Chengyang
    Chu, Wei
    Zhou, Yuanlin
    Koehler, Klaus
    CHEMISTRYSELECT, 2016, 1 (12): : 3197 - 3203