Effect of Support Materials on the Selective Methanation of CO over Ru Catalysts

被引:38
|
作者
Urasaki, Kohei [1 ]
Endo, Ken-ichiro [1 ]
Takahiro, Tomoki [1 ]
Kikuchi, Ryuji [2 ]
Kojima, Toshinori [1 ]
Satokawa, Shigeo [1 ]
机构
[1] Seikei Univ, Fac Sci & Technol, Dept Mat & Life Sci, Musashino, Tokyo, Japan
[2] Univ Tokyo, Fac Engn, Dept Chem Syst Engn, Bunkyo Ku, Tokyo 113, Japan
关键词
Selective methanation; Ruthenium catalyst; Reformate gas; Support material; PREFERENTIAL OXIDATION; CARBON-MONOXIDE; HYDROGEN; GAS; REMOVAL; OXIDES;
D O I
10.1007/s11244-010-9509-5
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Selective methanation of CO in the reformate gas (CO/CO2/H-2/H2O = 0.175/17.9/70.9/11.1) proceeded over Ru catalysts supported on metal oxides and zeolites. CO was selectively methanated at wide temperature ranges (200-275 A degrees C) over Ru/gamma-Al2O3, Ru/TiO2 Ru/H-Y and Ru/H-beta catalysts. Higher Ru contents in Ru/gamma-Al2O3 improved the selective CO methanation rate.
引用
收藏
页码:707 / 711
页数:5
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