Mixed-ligand complexes of technetium .14. Structure of trans-[TcCl2(NCS)(Me(2)PhP)(3)]

被引：6

作者：

Abram, U ^{[1
]}

Abram, S ^{[1
]}

Dilworth, JR ^{[1
]}

机构：

[1] UNIV ESSEX,DEPT CHEM & BIOL CHEM,COLCHESTER CO4 3SQ,ESSEX,ENGLAND

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270195012923

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

mer-[TcCl3(Me(2)PhP)(3)] reacts with potassium thiocyanate with the replacement of only one Cl- ligand by NCS- and forms selectively (OC-6-12)-dichlorotris(dimethylphenylphosphine)(thiocyanato-kappa N)-technetium(III) {mer, trans-[TcCl2(NCS)(Me(2)PhP)(3)]}. No evidence could be found for the formation of the cis analogue, The title compound crystallizes in monomeric units. The Tc atom is coordinated in a distorted octahedral manner with the two Cl ligands in trans positions to each other. The NCS- ligand is N-bonded with a Tc-N bond length of 2.104 (3) Angstrom.

引用

页码：605 / 607

页数：3

共 16 条

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