Comparative analysis of Raman spectra of PbS macro- and nanocrystals

被引:28
作者
Baranov, A. V. [1 ]
Bogdanov, K. V. [1 ]
Ushakova, E. V. [1 ]
Cherevkov, S. A. [1 ]
Fedorov, A. V. [1 ]
Tscharntke, S. [2 ]
机构
[1] St Petersburg State Univ Informat Technol Mech &, St Petersburg 197101, Russia
[2] Tech Univ Dresden, D-01062 Dresden, Germany
关键词
QUANTUM DOTS; SCATTERING;
D O I
10.1134/S0030400X10080199
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
A comparative analysis of the Raman spectra of bulk PbS and PbS nanocrystals with average diameters of 6.6 and 3.8 nm has been performed. It is shown that the bands due to the LO phonons at the I" point of the Brillouin zone dominate in the first- and second-order Raman spectra of the nanocrystals. Based on the analysis of the relative band intensities for the first- and second-order spectra a qualitative conclusion is drawn: the electron-LO-phonon interaction in PbS nanocrystals increases with a decrease in their size.
引用
收藏
页码:268 / 271
页数:4
相关论文
共 16 条
[1]   Highly photoluminescent PbS nanocrystals: The beneficial effect of trioctylphosphine [J].
Abel, Keith A. ;
Shan, Jingning ;
Boyer, John-Christopher ;
Harris, Fraser ;
van Veggel, Frank C. J. M. .
CHEMISTRY OF MATERIALS, 2008, 20 (12) :3794-3796
[2]   CRYSTAL DYNAMICS OF LEAD SULPHIDE [J].
ELCOMBE, MM .
PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1967, 300 (1461) :210-&
[3]   Temperature-dependent Raman scattering of natural and isotopically substituted PbS [J].
Etchegoin, P. G. ;
Cardona, M. ;
Lauck, R. ;
Clark, R. J. H. ;
Serrano, J. ;
Romero, A. H. .
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2008, 245 (06) :1125-1132
[4]   Exciton-phonon coupling in semiconductor quantum dots: Resonant Raman scattering [J].
Fedorov, AV ;
Baranov, AV ;
Inoue, K .
PHYSICAL REVIEW B, 1997, 56 (12) :7491-7502
[5]  
FEDOROV AV, 2005, OPTICS NANOSTRUCTURE, P181
[6]   FACTOR GROUP ANALYSIS FOR SOME COMMON MINERALS [J].
FERRARO, JR .
APPLIED SPECTROSCOPY, 1975, 29 (05) :418-421
[7]   Theoretical study of the electronic structure of PbS nanoclusters [J].
Kane, RS ;
Cohen, RE ;
Silbey, R .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (19) :7928-7932
[8]   Raman-scattering study of exciton-phonon coupling in PbS nanocrystals [J].
Krauss, TD ;
Wise, FW .
PHYSICAL REVIEW B, 1997, 55 (15) :9860-9865
[9]  
MADELUNG O, 1983, LANDOLTBORNSTEIN N F, V17
[10]  
MADELUNG O, 2005, LANDOLTBORNSTEIN G A, V41