Sulfur-imine mixed donor chelate ligands for asymmetric catalysis: enantioselective allylic alkylation

被引：67

作者：

Anderson, JC ^{[1
]}

James, DS

Mathias, JP

机构：

[1] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

[2] Pfizer Ltd, Cent Res, Sandwich CT13 9NJ, Kent, England

来源：

TETRAHEDRON-ASYMMETRY | 1998年 / 9卷 / 05期

关键词：

D O I：

10.1016/S0957-4166(98)00057-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new series of sulfur-imine mixed donor chiral ligands, prepared in only two steps from commercially available (S)-valinol, have been shown to give up to 94% enantiomeric excess in a palladium-catalysed allylic substitution reaction. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：753 / 756

页数：4

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