Heteropolynuclear sodium(I) lead(II) complex:: Crystal and molecular structure of a novel 3-D polymer, [(en)Pb(μ3-ONO)2Na(μ3-ONO)2Na(μ-O2ClO2)Na]n

被引：10

作者：

Morsali, A

Chen, XM

机构：

[1] Tarbiat Modares Univ, Sch Med, Dept Chem, Tehran, Iran

[2] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China

来源：

HELVETICA CHIMICA ACTA | 2004年 / 87卷 / 12期

关键词：

D O I：

10.1002/hlca.200490274

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel 3D polymeric heteropolynuclear sodium(I) lead(II) complex containing different ligands, [NaPb(ClO4)(en)(NO2)(2)] was synthesized and characterized by elemental analysis and IR, and H-1-, C-13-, and Pb-207-NMR spectroscopy. The single-crystal X-ray data of [NaPb(ClO4)(en)(NO2)2]. established that the complex is a three-dimensional polymer, [(en)Pb(mu(3)-ONO)(2)Na(mu(3)-ONO)(2)Na(mu-O2Cl0O2Na](n). The Pb and Na atoms have four- and eight-coordinate geometry, respectively. The lone pair of electrons at the Pb-II atom is 'stereochemically active'.

引用

收藏

页码：3050 / 3055

页数：6

相关论文

共 13 条

[1] Crystal engineering and organometallic architecture [J].

Braga, D ;

Grepioni, F ;

Desiraju, GR .

CHEMICAL REVIEWS, 1998, 98 (04) :1375-1405

[2] STRUCTURE-DEPENDENT AND ORIENTATION-DEPENDENT MAGNETIC-SUSCEPTIBILITY OF TETRAMETHYLAMMONIUM NICKEL NITRITE, (CH3)4N[NI(NO2)3] - AN S=1 ONE-DIMENSIONAL HEISENBERG-ANTIFERROMAGNET [J].

CHOU, LK ;

ABBOUD, KA ;

TALHAM, DR ;

KIM, WW ;

MEISEL, MW .

CHEMISTRY OF MATERIALS, 1994, 6 (11) :2051-2055

[3] STRUCTURAL AND SPECTROSCOPIC STUDIES OF TRANSITION-METAL NITRITE COMPLEXES .8. CRYSTAL-STRUCTURES AND SPECTRA OF 3 PENTANUCLEAR SPECIES WITH STOICHIOMETRY [NI5(N-SUBSTITUTED ETHANE-1,2-DIAMINE)4(OH)2(NO2)8] [J].

FINNEY, AJ ;

HITCHMAN, MA ;

RASTON, CL ;

ROWBOTTOM, GL ;

WHITE, AH .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1981, 34 (10) :2139-2157

[4] On the structure of transition-metal-linked molecular squares [J].

Fujita, M ;

Sasaki, O ;

Mitsuhashi, T ;

Fujita, T ;

Yazaki, J ;

Yamaguchi, K ;

Ogura, K .

CHEMICAL COMMUNICATIONS, 1996, (13) :1535-1536

[5] CRYSTAL-STRUCTURE AND SPECTROSCOPIC AND MAGNETIC-PROPERTIES OF A NOVEL NICKEL(II) DIMER CONTAINING A TRIDENTATE NITRITE GROUP - [NI(NH2CH2CH2NH2)2NO2]2[B(C6H5)4]2 [J].

GLEIZES, A ;

MEYER, A ;

HITCHMAN, MA ;

KAHN, O .

INORGANIC CHEMISTRY, 1982, 21 (06) :2257-2263

[6] CRYSTAL STRUCTURE OF [NI(BETA-PICOLINE)2(NO2)2]3.C6H6 - A LINEAR TRIMER WITH A NOVEL NITRITE BRIDGE [J].

GOODGAME, DM ;

HITCHMAN, MA ;

MARSHAM, DF ;

PHAVANAN.P ;

ROGERS, D .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1969, (23) :1383-&

[7] Nanoscale tectonics: Self-assembly, characterization, and chemistry of a novel class of organoplatinum square macrocycles [J].

Manna, J ;

Kuehl, CJ ;

Whiteford, JA ;

Stang, PJ ;

Muddiman, DC ;

Hofstadler, SA ;

Smith, RD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (48) :11611-11619

[8]

MORSALI A, 2003, CHEM LETT, P65

[9] From molecules to crystal engineering: Supramolecular isomerism and polymorphism in network solids [J].

Moulton, B ;

Zaworotko, MJ .

CHEMICAL REVIEWS, 2001, 101 (06) :1629-1658

[10] Synthesis and crystal structure of a new mononuclear compound containing alternate nickel(II) and sodium ions in the sheet [Ni(en)2(NO2)2]NaClO4•H2O [J].

Resino, I ;

Monfort, M ;

Ribas, J ;

Font-Bardia, M ;

Solans, X .

POLYHEDRON, 2000, 19 (02) :225-228