Thiol-ene polymer beads via liquid-liquid printing: armored interfaces and photopolymerization via graphitic carbon nitride

被引：5
作者：
Esen, Cansu [1 ]
Kumru, Baris [1 ,2 ]
机构：
[1] Max Planck Inst Colloids & Interfaces, Dept Colloid Chem, Muhlenberg 1, D-14424 Potsdam, Germany
[2] Delft Univ Technol, Fac Aerosp Engn, Dept Aerosp Struct & Mat, Kluyverweg 1, NL-2629 HS Delft, Netherlands
来源：
NANOSCALE ADVANCES | 2022年 / 4卷 / 15期
关键词：
QUANTUM DOTS; MONOLITH;
D O I：
10.1039/d2na00254j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Polymerization of multifunctional thiol-ene molecules is attractive as a proof of concept in photopolymerization, yet the formation of a bead structure is highly restricted. This manuscript will show graphitic carbon nitride based liquid-liquid printing and subsequent photopolymerization to form thiol-ene polymer beads with extreme simplicity and potential scalability.
引用
收藏
页码：3136 / 3141
页数：6
相关论文
共 40 条
[1]   Nanoarchitectonics, now [J].
Azzaroni, Omar ;
Ariga, Katsuhiko .
MOLECULAR SYSTEMS DESIGN & ENGINEERING, 2019, 4 (01) :9-10
[2]   Nickel on nitrogen-doped carbon pellets for continuous-flow hydrogenation of biomass-derived compounds in water [J].
Brandi, Francesco ;
Baeumel, Marius ;
Molinari, Vaterio ;
Shekova, Irina ;
Lauermann, Iver ;
Heil, Tobias ;
Antonietti, Markus ;
Al-Naji, Majd .
GREEN CHEMISTRY, 2020, 22 (09) :2755-2766
[3]   Molding and Encoding Carbon Nitride-Containing Edible Oil Liquid Objects via Interfacial Toughening in Waterborne Systems [J].
Cao, Qian ;
Amini, Shahrouz ;
Kumru, Baris ;
Schmidt, Bernhard V. K. J. .
ACS APPLIED MATERIALS & INTERFACES, 2021, 13 (03) :4643-4651
[4]   Photoactive Graphitic Carbon Nitride-Based Gel Beads As Recyclable Photocatalysts [J].
Cao, Qian ;
Barrio, Jesus ;
Antonietti, Markus ;
Kumru, Baris ;
Shalom, Menny ;
Schmidt, Bernhard V. K. J. .
ACS APPLIED POLYMER MATERIALS, 2020, 2 (08) :3346-3354
[5]   Incorporating Graphitic Carbon Nitride (g-C3N4) Quantum Dots into Bulk-Heterojunction Polymer Solar Cells Leads to Efficiency Enhancement [J].
Chen, Xiang ;
Liu, Qing ;
Wu, Qiliang ;
Du, Pingwu ;
Zhu, Jun ;
Dai, Songyuan ;
Yang, Shangfeng .
ADVANCED FUNCTIONAL MATERIALS, 2016, 26 (11) :1719-1728
[6]   Polymer micro-particles formed by thiol-ene suspension polymerization using canola oil as a diluent solvent [J].
Cobb, Jared S. ;
Chapusha, Chipo ;
Gaikwad, Jui ;
Michael, Joshua ;
Janorkar, Amol, V .
MATERIALS ADVANCES, 2021, 2 (10) :3378-3384
[7]   Highly Tunable Thiol-Ene Photoresins for Volumetric Additive Manufacturing [J].
Cook, Caitlyn C. ;
Fong, Erika J. ;
Schwartz, Johanna J. ;
Porcincula, Dominique H. ;
Kaczmarek, Allison C. ;
Oakdale, James S. ;
Moran, Bryan D. ;
Champley, Kyle M. ;
Rackson, Charles M. ;
Muralidharan, Archish ;
McLeod, Robert R. ;
Shusteff, Maxim .
ADVANCED MATERIALS, 2020, 32 (47)
[8]   Phenyl-Modified Carbon Nitride Quantum Dots with Distinct Photoluminescence Behavior [J].
Cui, Qianling ;
Xu, Jingsan ;
Wang, Xiaoyu ;
Li, Lidong ;
Antonietti, Markus ;
Shalom, Menny .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (11) :3672-3676
[9]   Oxidative Photopolymerization of 3,4-Ethylenedioxythiophene (EDOT) via Graphitic Carbon Nitride: A Modular Toolbox for Attaining PEDOT [J].
Esen, Cansu ;
Antonietti, Markus ;
Kumru, Baris .
CHEMPHOTOCHEM, 2021, 5 (09) :857-862
[10]   Upgrading poly(styrene-co-divinylbenzene) beads: Incorporation of organomodified metal-free semiconductor graphitic carbon nitride through suspension photopolymerization to generate photoactive resins [J].
Esen, Cansu ;
Antonietti, Markus ;
Kumru, Baris .
JOURNAL OF APPLIED POLYMER SCIENCE, 2021, 138 (35)
1234