An efficient metal- and solvent-free organocatalytic system for chemical fixation of CO2 into cyclic carbonates under mild conditions

被引：204

作者：

Wang, Lin ^{[1
]}

Zhang, Guangyou ^{[2
]}

Kodama, Koichi ^{[1
]}

Hirose, Takuji ^{[1
]}

机构：

[1] Saitama Univ, Grad Sch Sci & Engn, Sakura Ku, 255 Shimo Okubo, Saitama 3388570, Japan

[2] Univ Jinan, Sch Chem & Chem Engn, Jinan 250022, Peoples R China

来源：

GREEN CHEMISTRY | 2016年 / 18卷 / 05期

关键词：

ORGANIC CARBONATES; PROPYLENE CARBONATE; HOMOGENEOUS CATALYST; IONIC LIQUID; DIOXIDE; EPOXIDES; TRANSFORMATION; CYCLOADDITION; COMPLEXES; HALIDES;

D O I：

10.1039/c5gc02697k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient, metal- and solvent-free catalytic system was developed for the conversion of CO2 and epoxides to the corresponding cyclic carbonates under mild conditions (T = 25-45 degrees C, 1 atm CO2) in high-to-excellent yields. The catalyst could be easily recycled, providing a more sustainable process for the chemical fixation of CO2.

引用

页码：1229 / 1233

页数：5

共 53 条

[1]

Baldwin A.M.H., 2014, CHEMSUSCHEM, V7, P3275

[2] Synthesis of Cyclic Carbonates from Epoxides and Carbon Dioxide by Using Bifunctional One-Component Phosphorus-Based Organocatalysts [J].

Buettner, Hendrik ;

Steinbauer, Johannes ;

Werner, Thomas .

CHEMSUSCHEM, 2015, 8 (16) :2655-2669

[3] Bifunctional One-Component Catalysts for the Addition of Carbon Dioxide to Epoxides [J].

Buettner, Hendrik ;

Lau, Kornelia ;

Spannenberg, Anke ;

Werner, Thomas .

CHEMCATCHEM, 2015, 7 (03) :459-467

[4] Reactive applications of cyclic alkylene carbonates [J].

Clements, JH .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2003, 42 (04) :663-674

[5] Transformation of Carbon Dioxide with Homogeneous Transition-Metal Catalysts: A Molecular Solution to a Global Challenge? [J].

Cokoja, Mirza ;

Bruckmeier, Christian ;

Rieger, Bernhard ;

Herrmann, Wolfgang A. ;

Kuehn, Fritz E. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (37) :8510-8537

[6] Sustainable metal-based catalysts for the synthesis of cyclic carbonates containing five-membered rings [J].

Comerford, James W. ;

Ingram, Ian D. V. ;

North, Michael ;

Wu, Xiao .

GREEN CHEMISTRY, 2015, 17 (04) :1966-1987

[7] ORGANOMETALLIC CHEMISTRY C-H carboxylation takes gold [J].

Dalton, Derek M. ;

Rovis, Tomislav .

NATURE CHEMISTRY, 2010, 2 (09) :710-711

[8] Carbon dioxide/epoxide coupling reactions utilizing lewis base adducts of zinc halides as catalysts. Cyclic carbonate versus polycarbonate production [J].

Darensbourg, DJ ;

Lewis, SJ ;

Rodgers, JL ;

Yarbrough, JC .

INORGANIC CHEMISTRY, 2003, 42 (02) :581-589

[9] Mechanistic aspects of the copolymerization reaction of carbon dioxide and epoxides, using a chiral salen chromium chloride catalyst [J].

Darensbourg, DJ ;

Yarbrough, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (22) :6335-6342

[10] Efficient carbonate synthesis under mild conditions through cycloaddition of carbon dioxide to oxiranes using a Zn(salphen) catalyst [J].

Decortes, Antonello ;

Martinez Belmonte, Marta ;

Benet-Buchholz, Jordi ;

Kleij, Arjan W. .

CHEMICAL COMMUNICATIONS, 2010, 46 (25) :4580-4582

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