Ba0.7Sr0.3TiO3-glass-silver percolative composite

被引:7
作者
Deepa, K. S. [1 ]
Priyatha, P. L. [1 ]
Parameswaran, P. [2 ]
Sebastian, M. T. [1 ]
James, J. [1 ]
机构
[1] CSIR, NIIST, Thiruvananthapuram 695019, Kerala, India
[2] Indira Gandhi Ctr Atom Res, Div Phys Met, Kalpakkam 603102, Tamil Nadu, India
关键词
Composites; Dielectric properties; Electrical conductivity; Glass; DIELECTRIC-PROPERTIES; SILVER;
D O I
10.1016/j.ceramint.2009.06.019
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Ba0.7Sr0.3TiO3-glass-silver (BST-glass-Ag) composites were prepared by the solid state ceramic route. Their percolation behavior and dielectric properties were examined. The pure BST had a percolation limit of 24 vol% of silver whereas an addition of 8 wt% of 50PbO-30B(2)O(3)-20SiO(2) (PBS) glass lowered the percolation limit to 14 vol% of Ag. Glass addition lowered the sintering temperature of BST from 1300 to 975 degrees C and addition of Ag further lowered the sintering temperature to 925 degrees C, minimizing the Ag loss during sintering. The relative permittivity increased from 2700 for pure BST to about five orders of magnitude in the BST-glass-Ag composites near the percolation threshold. (C) 2009 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码:75 / 78
页数:4
相关论文
共 17 条
[1]  
Assal J, 1997, J AM CERAM SOC, V80, P3054, DOI 10.1111/j.1151-2916.1997.tb03232.x
[2]   Evaporation of silver during cofiring with barium titanate [J].
Chen, CY ;
Tuan, WH .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2000, 83 (07) :1693-1698
[3]   THEORY OF RESONANT MODES IN PARTICULATE MATTER [J].
CLARO, F .
PHYSICAL REVIEW B, 1984, 30 (09) :4989-4999
[4]   Effect of interparticle distance and interfacial area on the properties of insulator-conductor composites [J].
Deepa, K. S. ;
Sebastian, M. T. ;
James, J. .
APPLIED PHYSICS LETTERS, 2007, 91 (20)
[5]   Inorganic ceramic/polymer ferroelectric composite electrets [J].
Dias, CJ ;
DasGupta, DK .
IEEE TRANSACTIONS ON DIELECTRICS AND ELECTRICAL INSULATION, 1996, 3 (05) :706-734
[6]   Effect of sintering temperature on the percolation threshold and the dielectric properties Ca[(Li1/3Nb2/3)1-x Tix]O3-δ - Ag composite [J].
George, Sumesh ;
Sebastian, Mailadil Thomas .
COMPOSITES SCIENCE AND TECHNOLOGY, 2008, 68 (12) :2461-2467
[7]   Giant permittivity of a bismuth zinc niobate-silver composite [J].
George, Sumesh ;
James, Jose ;
Sebastian, Mailadil Thomas .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2007, 90 (11) :3522-3528
[8]  
HUANG J, 2008, APPL PHYS LETT, V92
[9]   Dense, fine-grained Ba1-xSrTiO3 ceramics prepared by the combination of mechanosynthesized nanopowders and spark plasma sintering [J].
Hungría, T ;
Algueró, M ;
Hungría, AB ;
Castro, A .
CHEMISTRY OF MATERIALS, 2005, 17 (24) :6205-6212
[10]   Interfaces: nanometric dielectrics [J].
Lewis, TJ .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2005, 38 (02) :202-212