The photochemical reaction between chlorine and chlorine perchlorate at 366 nm

被引：7
作者：
Lopez, MI [1 ]
Croce, AE [1 ]
Sicre, JE [1 ]
机构：
[1] Natl Univ La Plata, Fac Ciencias Exactas, Dept Quim, Inst Invest Fisicoquim Teor & Aplicadas, RA-1900 La Plata, Argentina
来源：
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 1998年 / 112卷 / 2-3期
关键词：
photochemical reaction; chlorine; chlorine perchlorate;
D O I：
10.1016/S1010-6030(97)00276-1
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The photolysis of Cl-2 in the presence of Cl2O4 at 366 nm in the gaseous phase has been investigated at 303 K. The UV absorbance of the gas mixture has been recorded spectrophotometrically after each photolysis interval to monitor the reactant Cl2O4 pressure and determine quantitatively the chlorinated reaction products. A quantum yield for Cl2O4 consumption of 2.0 +/- 0.2 has been determined. The main reaction products are Cl2O7, Cl-2 and O-2, accompanied by small quantities of Cl2O6 and OClO. A mechanism involving ClO4 radicals formed in the Cl atom abstraction from Cl2O4 by Cl is proposed. (C) 1998 Elsevier Science S.A.
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收藏
页码：97 / 102
页数：6
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