The in Situ NHC-Palladium Catalyzed Selective Activation of B(3)-H or B(6)-H Bonds of o-Carboranes for Hydroboration of Alkynes: An Efficient Approach to Alkenyl-o-carboranes

被引：26

作者：

Cao, Ke ^{[1
,2
]}

Xu, Tao-Tao ^{[1
,2
]}

Wu, Ji ^{[1
,2
]}

Zhang, Cai-Yan ^{[1
,2
]}

Wen, Xin-Yu ^{[1
,2
]}

Yang, Junxiao ^{[1
,2
]}

机构：

[1] Southwest Univ Sci & Technol, State Key Lab Environm Friendly Energy Mat, Mianyang 621010, Sichuan, Peoples R China

[2] Southwest Univ Sci & Technol, Sch Mat Sci & Engn, Mianyang 621010, Sichuan, Peoples R China

来源：

INORGANIC CHEMISTRY | 2021年 / 60卷 / 02期

基金：

中国国家自然科学基金;

关键词：

CAGE B-H; N-HETEROCYCLIC CARBENES; STRUCTURAL-CHARACTERIZATION; OXIDATIVE ADDITION; BORON; IRIDIUM; ARYLATION; ACID; COMPLEXES; CHEMISTRY;

D O I：

10.1021/acs.inorgchem.0c03203

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An in situ Pd-NHC catalyzed selective B(3,6)-H activation for hydroboration of internal alkynes has been accomplished under mild conditions. This work offers a facile approach for the synthesis of alkenyl-o-carboranes and has important reference for selective functionalization of B(3,6)-H bonds.

引用

页码：1081 / 1086

页数：6

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