Bridged aminotroponiminate complexes of lutetium

被引：12
|
作者：
Roesky, PW [1 ]
机构：
[1] Univ Karlsruhe, Inst Anorgan Chem, D-76128 Karlsruhe, Germany
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2000年 / 603卷 / 02期
关键词：
aminotroponiminate; coordination chemistry; lanthanides; lutetium; N-ligands;
D O I：
10.1016/S0022-328X(00)00157-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of the salt di-potassium-1,3-di(2-(isopropylamino)troponiminate)-propane, K-2[(Pr-i)TP], with lutetium trichloride leads to [[(Pr-i)TP]LuCl](2) (1). 1 was characterized by single crystal X-ray crystallography. To study the reactivity of 1 some selected derivatives such as alkyl, amide, eta(5)-cyclopentadienyl, and eta(3)-borohydride complexes were synthesized by substitution of the chlorine atom of 1. (C) 2000 Published by Elsevier Science S.A. All rights reserved.
引用
收藏
页码：161 / 166
页数：6
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