Bridged aminotroponiminate complexes of lutetium

被引：12
|
作者：
Roesky, PW [1 ]
机构：
[1] Univ Karlsruhe, Inst Anorgan Chem, D-76128 Karlsruhe, Germany
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2000年 / 603卷 / 02期
关键词：
aminotroponiminate; coordination chemistry; lanthanides; lutetium; N-ligands;
D O I：
10.1016/S0022-328X(00)00157-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of the salt di-potassium-1,3-di(2-(isopropylamino)troponiminate)-propane, K-2[(Pr-i)TP], with lutetium trichloride leads to [[(Pr-i)TP]LuCl](2) (1). 1 was characterized by single crystal X-ray crystallography. To study the reactivity of 1 some selected derivatives such as alkyl, amide, eta(5)-cyclopentadienyl, and eta(3)-borohydride complexes were synthesized by substitution of the chlorine atom of 1. (C) 2000 Published by Elsevier Science S.A. All rights reserved.
引用
收藏
页码：161 / 166
页数：6
相关论文
共 50 条
  • [1] Bridged aminotroponiminate complexes of the lanthanides
    Roesky, PW
    Bürgstein, MR
    INORGANIC CHEMISTRY, 1999, 38 (24) : 5629 - +
  • [2] Bridged aminotroponiminate complexes of zinc
    Gamer, MT
    Roesky, PW
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2003, (11) : 2145 - 2148
  • [3] Bridged aminotroponiminate complexes of lanthanum
    Roesky, PW
    INORGANIC CHEMISTRY, 1998, 37 (18) : 4507 - 4511
  • [4] Chiral bridged aminotroponiminate complexes of the lanthanides
    Meyer, Nils
    Roesky, Peter W.
    DALTON TRANSACTIONS, 2007, (25) : 2652 - 2657
  • [5] Bridged aminotroponiminate complexes of gallium and indium
    Bürgstein, MR
    Euringer, NP
    Roesky, PW
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (07): : 1045 - 1048
  • [6] A chiral-bridged aminotroponiminate complex of lutetium as catalyst for the asymmetric hydroamination
    Meyer, Nils
    Zulys, Agustino
    Roesky, Peter W.
    ORGANOMETALLICS, 2006, 25 (17) : 4179 - 4182
  • [7] Chiral bridged aminotroponiminate complexes of the heavy lanthanides
    Bürgstein, MR
    Roesky, PW
    ORGANOMETALLICS, 2003, 22 (07) : 1372 - 1375
  • [8] Chiral Aminotroponiminate Zinc Complexes
    Meyer, Nils
    Roesky, Peter W.
    ORGANOMETALLICS, 2009, 28 (01) : 306 - 311
  • [9] Aminotroponiminate calcium and strontium complexes
    Datta, Simmi
    Gamer, Michael T.
    Roesky, Peter W.
    DALTON TRANSACTIONS, 2008, (21) : 2839 - 2843
  • [10] Aminotroponiminate alkyl and alkoxide complexes of zinc
    Herrmann, JS
    Luinstra, GA
    Roesky, PW
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (16) : 2720 - 2725
12345