Photoluminescence spectroscopy and positron annihilation spectroscopy probe of alloying and annealing effects in nonpolar m-plane ZnMgO thin films

被引:32
作者
Yang, A. L. [1 ]
Song, H. P. [1 ]
Liang, D. C. [1 ]
Wei, H. Y. [1 ]
Liu, X. L. [1 ]
Jin, P. [1 ]
Qin, X. B. [2 ]
Yang, S. Y. [1 ]
Zhu, Q. S. [1 ]
Wang, Z. G. [1 ]
机构
[1] Chinese Acad Sci, Inst Semicond, Key Lab Semicond Mat Sci, Beijing 100083, Peoples R China
[2] Chinese Acad Sci, Inst High Energy Phys, Key Lab Nucl Anal Tech, Beijing 100049, Peoples R China
基金
美国国家科学基金会;
关键词
alloying; annealing; electrical conductivity; excitons; II-VI semiconductors; magnesium compounds; MOCVD coatings; photoluminescence; positron annihilation; semiconductor thin films; vacancies (crystal); wide band gap semiconductors; zinc compounds; EMISSION; ORIGIN;
D O I
10.1063/1.3394012
中图分类号
O59 [应用物理学];
学科分类号
摘要
Temperature-dependent photoluminescence characteristics of non-polar m-plane ZnO and ZnMgO alloy films grown by metal organic chemical vapor deposition have been studied. The enhancement in emission intensity caused by localized excitons in m-plane ZnMgO alloy films was directly observed and it can be further improved after annealing in nitrogen. The concentration of Zn vacancies in the films was increased by alloying with Mg, which was detected by positron annihilation spectroscopy. This result is very important to directly explain why undoped Zn1-xMgxO thin films can show p-type conduction by controlling Mg content, as discussed by Li [Appl. Phys. Lett. 91, 232115 (2007)].
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页数:3
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