Physical & enhanced photocatalytic properties of green synthesized SnO2 nanoparticles via Aspalathus linearis

被引:130
作者
Diallo, A. [1 ,2 ]
Manikandan, E. [1 ,2 ]
Rajendran, V. [1 ,2 ,3 ]
Maaza, M. [1 ,2 ]
机构
[1] Univ S Africa, Coll Grad Studies, UNESCO UNISA Africa Chair Nanosci Nanotechnol, POB 392, ZA-0001 Pretoria, South Africa
[2] iThemba LABS Natl Res Fdn, Nanosci African Network NANOAFNET, 1 Old Faure Rd,Somerset West 7129,POB 722, Somerset West, Western Cape, South Africa
[3] KS Rangasamy Coll Technol, Ctr Nano Sci & Nanotechnol, Tiruchengode 63721, Tamil Nadu, India
基金
新加坡国家研究基金会;
关键词
Green synthesis; Tin oxide; Nanoparticles; Aspalathus linearis extract; Photocatalytic response; OPTICAL-PROPERTIES; PHOTOLUMINESCENCE PROPERTIES; ELECTRICAL-PROPERTIES; CDO NANOPARTICLES; LASER-ABLATION; THIN-FILM; GROWTH; GAS; TEMPERATURE; SIZE;
D O I
10.1016/j.jallcom.2016.04.200
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This contribution reports on the synthesis and the main physical properties of n-type SnO2 nanoparticles synthesized for the first time by a completely green chemistry process using Aspalathus linearis's natural extract as an effective chelating agent. Their surface/interface and volume properties by X-rays diffraction, Raman, X-rays photoemission & photoluminescence spectroscopies are reported. Their average diameter ranging from 2.1 to 19.3 nm follows a thermal governed equation of < empty setparticles > = 1.048 10(-5) T-2 - 4.92 10(-3) T + 2.84. The smallest SnO2 nanoparticles exhibit effective photocatalytic responses to Methylene blue, Congo red and Eosin Y. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:561 / 570
页数:10
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