Innovation in solid heterogeneous catalysis for the generation of economically viable and ecofriendly biodiesel: A review

被引:85
作者
Avhad, M. R. [1 ]
Marchetti, J. M. [1 ]
机构
[1] Norwegian Univ Life Sci, Dept Math Sci & Technol, Drobakveien, Norway
来源
CATALYSIS REVIEWS-SCIENCE AND ENGINEERING | 2016年 / 58卷 / 02期
关键词
Acidic materials; alcoholysis; basic materials; biodiesel production; heterogenous catalysis; homogenous catalysis; WASTE COOKING OIL; FREE FATTY-ACID; ANION-EXCHANGE RESIN; RESPONSE-SURFACE METHODOLOGY; PONGAMIA-PINNATA OIL; SOYBEAN OIL; CALCIUM-OXIDE; VEGETABLE-OIL; SUNFLOWER OIL; SULFATED ZIRCONIA;
D O I
10.1080/01614940.2015.1103594
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Among the possible options for the transformation of plant oils and animal fats to biodiesel, the alcoholysis process has been frequently selected. The rate of alcoholysis reaction is accelerated using a catalytic material. This article reviews different nature of catalysts utilized to assist the process of biodiesel production. The chemical properties of both homogeneous and heterogeneous catalysts enable their sub-division into acidic and basic materials. The proficiency of several heterogeneous catalytic systems and the possible route of alcoholysis reaction using different materials is systematically discussed. Furthermore, the factors influencing the performance of catalysts are also considered.
引用
收藏
页码:157 / 208
页数:52
相关论文
共 158 条
[1]   Biofuels (alcohols and biodiesel) applications as fuels for internal combustion engines [J].
Agarwal, Avinash Kumar .
PROGRESS IN ENERGY AND COMBUSTION SCIENCE, 2007, 33 (03) :233-271
[2]   Heterogeneous transesterification processes by using CaO supported on zinc oxide as basic catalysts [J].
Alba-Rubio, Ana C. ;
Santamaria-Gonzalez, Jose ;
Merida-Robles, Josefa M. ;
Moreno-Tost, Ramon ;
Martin-Alonso, David ;
Jimenez-Lopez, Antonio ;
Maireles-Torres, Pedro .
CATALYSIS TODAY, 2010, 149 (3-4) :281-287
[3]   Biodiesel production by acid catalysis with heteropolyacids supported on activated carbon fibers [J].
Alcaniz-Monge, Juan ;
Trautwein, Guido ;
Pablo Marco-Lozar, Juan .
APPLIED CATALYSIS A-GENERAL, 2013, 468 :432-441
[4]   Production of biodiesel from mixed waste vegetable oils using Ferric hydrogen sulphate as an effective reusable heterogeneous solid acid catalyst [J].
Alhassan, Fatah H. ;
Yunus, Robiah ;
Rashid, Umer ;
Sirat, Kamaliah ;
Islam, Aminul ;
Lee, H. V. ;
Taufiq-Yap, Yun H. .
APPLIED CATALYSIS A-GENERAL, 2013, 456 :182-187
[5]   Magnesium oxide prepared via metal-chitosan complexation method: Application as catalyst for transesterification of soybean oil and catalyst deactivation studies [J].
Almerindo, Gizelle I. ;
Probst, Luiz F. D. ;
Campos, Carlos E. M. ;
de Almeida, Rusiene M. ;
Meneghetti, Simoni M. P. ;
Meneghetti, Mario R. ;
Clacens, Jean-Marc ;
Fajardo, Humberto V. .
JOURNAL OF POWER SOURCES, 2011, 196 (19) :8057-8063
[6]   Residual animal fat and fish for biodiesel production. Potentials in Norway [J].
Andersen, Otto ;
Weinbach, Jan-Erik .
BIOMASS & BIOENERGY, 2010, 34 (08) :1183-1188
[7]   Synthesis of biodiesel with heterogeneous NaOH/alumina catalysts:: Comparison with homogeneous NaOH [J].
Arzamendi, G. ;
Campo, I. ;
Arguinarena, E. ;
Sanchez, M. ;
Montes, M. ;
Gandia, L. M. .
CHEMICAL ENGINEERING JOURNAL, 2007, 134 (1-3) :123-130
[8]   Synthesis of biodiesel from sunflower oil with silica-supported NaOH catalysts [J].
Arzamendi, Gurutze ;
Campo, Idoia ;
Arguinarena, Eider ;
Sanchez, Maialen ;
Montes, Mario ;
Gandia, Luis M. .
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2008, 83 (06) :862-870
[9]   Potassium hydroxide catalyst supported on palm shell activated carbon for transesterification of palm oil [J].
Baroutian, Saeid ;
Aroua, Mohamed Kheireddine ;
Raman, Abdul Aziz Abdul ;
Sulaiman, Nik Meriam Nik .
FUEL PROCESSING TECHNOLOGY, 2010, 91 (11) :1378-1385
[10]   Catalysis and fine chemistry [J].
Barrault, J ;
Pouilloux, Y ;
Clacens, JM ;
Vanhove, C ;
Bancquart, S .
CATALYSIS TODAY, 2002, 75 (1-4) :177-181