Synthesis and Characterization of New Aromatic-Group Substituted Silanes Bearing Tris (Trimethylsilyl)Methyl Bulky Groups

被引：0

作者：

Tarassoli, Abbas ^{[1
]}

Asadi, Ashrafolmolouk ^{[1
]}

机构：

[1] Shahid Chamran Univ, Coll Sci, Dept Chem, Ahvaz, Iran

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2010年 / 185卷 / 07期

关键词：

Bulky group; Grignard reagent; organosilicon; steric hindrance; trisyl; CRYSTAL-STRUCTURES; ORGANOMETALLIC COMPOUNDS; TRIS(TRIMETHYLSILYL)METHYL; DERIVATIVES; ALKYL; CHLORINE;

D O I：

10.1080/10426500903074866

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of the Grignard reagent, p-ClC6H4MgCl, with SiCl4 in toluene gave (p-ClC6H4)2SiCl2, which was treated with KHF2 to give (p-ClC6H4)2SiF2 (1). Reaction of the latter with [(Me3Si)3C]Li in THF leads to the preparation of [(Me3Si)3C](p-ClC6H4)2SiF (2). Treatment of (2) with LiAlH4 gave [(Me3Si)3C](p-ClC6H4)2SiH (3) and [(Me3Si)3C](p-ClC6H4)(C6H5)SiH (4). [(Me3Si)3C](p-ClC6H4)SiCl2 (5) was also prepared from the reaction of (p-ClC6H4)SiCl3 with [(Me3Si)3C]Li in a similar manner. The new highly sterically hindered organosilicon reagents (2) to (5) have been fully characterized by IR, 1H and 13C NMR, and mass spectrometry as well as elemental analysis.

引用

页码：1463 / 1468

页数：6

共 30 条

[1] METALATION OF TRIS(TRIMETHYLSILYL)METHANE AND TRIS(DIMETHYLPHENYLSILYL)METHANE WITH METHYLSODIUM - THE FIRST DIALKYLSODATE [J].

ALJUAID, SS ;

EABORN, C ;

HITCHCOCK, PB ;

IZOD, K ;

MALLIEN, M ;

SMITH, JD .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (12) :1268-1270

[2] HYDROGEN-BONDING IN ORGANOSILANETRIOLS - THE CRYSTAL-STRUCTURES OF TRIS(TRIMETHYLSILYL)SILYL-SILANETRIOLS AND TRIS(TRIMETHYLSILYL)-METHYL-SILANETRIOLS [J].

ALJUAID, SS ;

BUTTRUS, NH ;

DAMJA, RI ;

DEROUICHE, Y ;

EABORN, C ;

HITCHCOCK, PB ;

LICKISS, PD .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 371 (03) :287-295

[3] THE GEOMETRY OF SIOCN AND SINCO LINKAGES - THE CRYSTAL-STRUCTURES OF (ME(3)SI)(2)(PH(2)MESI)CSIME(2)OCN AND (PHME(2)SI)(3)CSIME(2)NCO [J].

ALJUAID, SS ;

ALNASR, AAK ;

AYOKO, GA ;

EABORN, C ;

HITCHCOCK, P .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 488 (1-2) :155-160

[4] PREPARATION, CRYSTAL-STRUCTURE, AND REACTIVITY OF BIS(TRIS(TRIMETHYLSILYL)METHYL)MAGNESIUM [J].

ALJUAID, SS ;

EABORN, C ;

HITCHCOCK, PB ;

KUNDU, K ;

MCGEARY, CA ;

SMITH, JD .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 480 (1-2) :199-203

[5] Synthesis and crystal structures of some cobalt halide derivatives containing alkyl or silanolato groups [J].

Asadi, A ;

Eaborn, C ;

Hill, MS ;

Hitchcock, PB ;

Smith, JD .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2005, 690 (04) :944-951

[6] Synthesis and crystal structures of organometallic compounds containing the ligands C(SiMe3)2(SiMe2H) and C(SiMe2Ph)2(SiMe2H) [J].

Asadi, A ;

Avent, AG ;

Coles, MP ;

Eaborn, C ;

Hitchcock, PB ;

Smith, JD .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (07) :1238-1248

[7] ALKYL-SUBSTITUTED, SILYL-SUBSTITUTED, AND GERMYL-SUBSTITUTED THIOLATE, SELENOLATE, AND TELLUROLATE DERIVATIVES AND INTERCONVERSION OF SILYL SPECIES BY CHALCOGEN METATHESIS [J].

BONASIA, PJ ;

CHRISTOU, V ;

ARNOLD, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (15) :6777-6781

[8] THE CRYSTAL-STRUCTURE OF [(PMDETA)LI(MU-CL)LI(PMDETA)][LI(C(SIME3)3)2] [PMDETA = ME2N(CH2)2NME(CH2)2NME2] - A NOVEL LINEAR CHLORINE-CENTERD CATION [J].

BUTTRUS, NH ;

EABORN, C ;

HITCHCOCK, PB ;

SMITH, JD ;

STAMPER, JG ;

SULLIVAN, AC .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (12) :969-970

[9] TRIS(TRIMETHYLSILYL)METHYL!LITHIUM - AN ALKYLLITHIUM COMPOUND OF UNUSUAL STABILITY [J].

COOK, MA ;

EABORN, C ;

JUKES, AE ;

WALTON, DRM .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1970, 24 (03) :529-&

[10] PREPARATION OF TRIS(TRIMETHYLSILYL)METHYL (TRISYL) DERIVATIVES OF SILICON [J].

DUA, SS ;

EABORN, C ;

HAPPER, DAR ;

HOPPER, SP ;

SAFA, KD ;

WALTON, DRM .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 178 (01) :75-82

← 1 2 3 →