Preparation of Charge-transfer Host Complex Composed of [9,9′-Biphenanthryl]-10,10′-diol Having a Large and Widely π-Conjugated Phenanthrene Ring

被引：3

作者：

Ukegawa, Tatsuya ^{[1
]}

Kinuta, Takafumi ^{[1
]}

Sato, Tomohiro ^{[2
]}

Tajima, Nobuo ^{[3
]}

Kuroda, Reiko ^{[2
,4
]}

Matsubara, Yoshio ^{[1
]}

Imai, Yoshitane ^{[1
]}

机构：

[1] Kinki Univ, Dept Appl Chem, Fac Sci & Engn, Higashiosaka, Osaka 5778502, Japan

[2] JST ERATO SORST Kuroda Chiromorphol Team, Meguro Ku, Tokyo 1530041, Japan

[3] Univ Tsukuba, Grad Sch Pure & Appl Sci, Tsukuba, Ibaraki 3058571, Japan

[4] Univ Tokyo, Dept Life Sci, Grad Sch Arts & Sci, Meguro Ku, Tokyo 1538902, Japan

来源：

CHEMISTRY LETTERS | 2010年 / 39卷 / 03期

关键词：

CORRELATED MOLECULAR CALCULATIONS; GAUSSIAN-BASIS SETS; SYSTEM;

D O I：

10.1246/cl.2010.257

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A colored supramolecular charge-transfer (CT) host complex composed of racemic rac-[9,9 '-biphenanthryl]-10,10 '-diol, having a large and widely pi-conjugated phenanthrene ring, as an electron donor and 2,5-dimethyl-1,4-benzoquinone as an electron acceptor has been developed. The molecular recognition properties (guest inclusion behavior and color) of the CT complex can be tuned by using electron donor molecules with different steric bulkiness and electron-donating properties.

引用

页码：257 / 259

页数：3

共 17 条

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