Polymerization of styrene with autoxidized methyl linoleate as radical initiator

被引：0

作者：

Kondo, M ^{[1
]}

Aikawa, S ^{[1
]}

Tasaka, S ^{[1
]}

Inagaki, N ^{[1
]}

机构：

[1] Shizuoka Univ, Fac Engn, Hamamatsu, Shizuoka 4328011, Japan

来源：

KOBUNSHI RONBUNSHU | 1998年 / 55卷 / 03期

关键词：

methyl linoleate; autoxidation; polymerization; styrene; radical;

D O I：

10.1295/koron.55.130

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Autoxidized methyl linoleate was used as the initiator of radical polymerization of styrene and the influence of the oxidation levels an the structure of resulting polymers a as investigated. Autoxidized methyl linoleate contained mainly monomers and oligomers with hydroperoxide moieties. They are able to work not only as sir. initiator but also as a crosslinking agent for the polymerization of styrene, The polymers synthesized by the oxidized products were not gelled and soluble in polar solvents completely. Therefore, the polymer was assumed to consist of linear (non-closslinked) chains having autoxidized methyl linoleate.

引用

页码：130 / 136

页数：7

共 10 条

[1]

BAWN CEH, 1953, J OIL COLOUR CHEM AS, V36, P443

[2]

CANON JA, 1952, J AM OIL CHEM SOC, V29, P447

[3]

GREQAVES JEH, 1948, OIL COLOUR TRADE J, V113, P949

[4]

Kappelmeier C. P. A., 1933, FARBEN ZTG, V38, P1018

[5] PHOTOSENSITIZED OXIDATION OF METHYL LINOLENATE - SECONDARY PRODUCTS [J].

NEFF, WE ;

FRANKEL, EN ;

WEISLEDER, D .

LIPIDS, 1982, 17 (11) :780-790

[6] HIGH-PRESSURE LIQUID-CHROMATOGRAPHY OF AUTO-OXIDIZED LIPIDS .2. HYDROPEROXY-CYCLIC PEROXIDES AND OTHER SECONDARY PRODUCTS FROM METHYL LINOLENATE [J].

NEFF, WE ;

FRANKEL, EN ;

WEISLEDER, D .

LIPIDS, 1981, 16 (06) :439-448

[7] PHOTOSENSITIZED OXIDATION OF METHYL LINOLEATE MONOHYDROPEROXIDES - HYDROPEROXY CYCLIC PEROXIDES, DIHYDROPEROXIDES, KETO ESTERS AND VOLATILE THERMAL-DECOMPOSITION PRODUCTS [J].

NEFF, WE ;

FRANKEL, EN ;

SELKE, E ;

WEISLEDER, D .

LIPIDS, 1983, 18 (12) :868-876

[8] HIGH-PRESSURE LIQUID-CHROMATOGRAPHY OF AUTOXIDIZED LIPIDS .1. METHYL OLEATE AND LINOLEATE [J].

NEFF, WE ;

FRANKEL, EN ;

SCHOLFIELD, CR ;

WEISLEDER, D .

LIPIDS, 1978, 13 (06) :415-421

[9]

OLUNDBERG W, 1962, J AM CHEM SOC, V69, P833

[10] INITIAL STAGES OF AUTOXIDATION [J].

PRIVETT, OS ;

BLANK, ML .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1962, 39 (11) :465-&

← 1 →