Phase transformation behaviours of Ti-Ni and Ti-Ni-Cu shape memory alloy powders fabricated by mechanical alloying
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Nam, TH
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Gyeong Sang Natl Univ, Dept Mat & Met Engn, Chinju 660701, Gyeong Nam, South KoreaGyeong Sang Natl Univ, Dept Mat & Met Engn, Chinju 660701, Gyeong Nam, South Korea
Nam, TH
[1
]
Hur, SG
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Gyeong Sang Natl Univ, Dept Mat & Met Engn, Chinju 660701, Gyeong Nam, South KoreaGyeong Sang Natl Univ, Dept Mat & Met Engn, Chinju 660701, Gyeong Nam, South Korea
Hur, SG
[1
]
Ahn, IS
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Gyeong Sang Natl Univ, Dept Mat & Met Engn, Chinju 660701, Gyeong Nam, South KoreaGyeong Sang Natl Univ, Dept Mat & Met Engn, Chinju 660701, Gyeong Nam, South Korea
Ahn, IS
[1
]
机构:
[1] Gyeong Sang Natl Univ, Dept Mat & Met Engn, Chinju 660701, Gyeong Nam, South Korea
Ti-Ni and Ti-Ni-Cu alloy powders have been fabricated by mechanical alloying, and then phase transformation behaviours were investigated by means of X-ray diffraction, scanning electron microscopy, energy dispersive X-ray analysis and transmision electron microscopy. The size of Ti-Ni-Cu alloy powders obtained decreased by increasing Cu-content. The powders of as-milled Ti-Ni and Ti-Ni-Cu alloys whose Cu-contents are less than 5 ato/o were amorphous, whereas those of as-milled Ti-Ni-Cu alloys whose Cu-content is more than 10 at% were crystalline. This means that Cu addition tends to suppress amorphization of Ti-Ni based alloy powders. The monoclinic B19' martensite is formed in the Ti-Ni-Cu alloy powders whose Cu-content is less than 10 at%, whereas the orthorhombic B19 martensite is formed in those whose Cu-content is more than 10 at%. The Fe contamination is reduced by decreasing rotating speed from 350 rpm to 250 rpm.