Bisphenol A Analysis in Food Samples Using Modified Nanostructure Carbon Paste Electrode as a Sensor

被引:39
作者
Arabali, Vahid [1 ]
Ebrahimi, Mahmoud [1 ]
Gheibi, Siamak [2 ]
Khaleghi, Fatemeh [3 ]
Bijad, Majede [4 ]
Rudbaraki, Ali [4 ]
Abbasghorbani, Maryam [5 ]
Ganjali, M. R. [6 ]
机构
[1] Islamic Azad Univ, Mashhad Branch, Dept Chem, Mashhad, Iran
[2] Univ Guilan, Dept Food Sci & Technol, Fac Agr Sci, Rasht, Iran
[3] Mazandaran Univ Med Sci, Hlth Plant & Livestock Prod Res Ctr, Sari, Iran
[4] Islamic Azad Univ, Dept Chem, Sari Branch, Sari, Iran
[5] Res Inst Petr Ind, Gas Div, POB 14665-137, Tehran, Iran
[6] Univ Tehran, Fac Chem, Ctr Excellence Electrochem, Tehran, Iran
关键词
Bisphenol A analysis; CdO nanoparticles; Voltammetry; Modified electrode; SENSITIVE VOLTAMMETRIC SENSOR; IONIC LIQUIDS RTILS; NIO/CNTS NANOCOMPOSITE; GRAPHITE ELECTRODE; NANOTUBES MWCNTS; GLASSY-CARBON; SUDAN I; MEMBRANE; BIOSENSOR; ACID;
D O I
10.1007/s12161-015-0349-6
中图分类号
TS2 [食品工业];
学科分类号
0832 ;
摘要
The electrochemical oxidation of bisphenol A has been studied by CdO nanoparticle ionic liquid carbon paste electrode. Cyclic voltammetry, square wave voltammetry, and chronoamperometry were used to investigate the suitability of new sensor for the electrooxidation of bisphenol A in aqueous solution. The electrooxidation of bisphenol A occurs at a potential about 50 mV less positive than with the unmodified carbon paste electrode at pH 7.0. The square wave voltammetry (SWV) peak currents of the electrode increased linearly with the corresponding bisphenol A concentration in the range of 0.3-650 mu M with a detection limit of 0.1 mu M. The influence of pH value and potential interfering substances on the determination of bisphenol A were studied. Finally, the proposed novel sensor was also examined as a sensitive, high selective, simple, and precise electrochemical sensor for the determination of bisphenol A in food samples.
引用
收藏
页码:1763 / 1769
页数:7
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