Synthetic utility and mechanistic implications of the fries rearrangement of hydroquinone diesters in boron trifluoride complexes

被引：35

作者：

Boyer, JL ^{[1
]}

Krum, JE ^{[1
]}

Myers, MC ^{[1
]}

Fazal, AN ^{[1
]}

Wigal, CT ^{[1
]}

机构：

[1] Lebanon Valley Coll, Dept Chem, Annville, PA 17003 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2000年 / 65卷 / 15期

关键词：

D O I：

10.1021/jo000412q

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reactions of boron trifluoride methyl and ethyl etherate complexes with hydroquinone diesters yield monomethyl and monoethyl derivatives of acetylhydroquinones, The use of sterically hindered boron trifluoride etherate complexes results in acetylhydroquinone derivatives. This procedure represents a one-step synthesis of acetylhydroquinone derivatives, important building blocks for a variety of synthetic applications.

引用

页码：4712 / 4714

页数：3

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